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Visar resultat 1 - 5 av 19 avhandlingar som matchar ovanstående sökkriterier.

1. 1. Zero-Field Splitting in Gd(III) complexes : Towards a molecular understanding of paramagnetic relaxation

   Författare :Shehryar Khan; Michael Odelius; Arnold Maliniak; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Zero-Field Splitting; Relaxation; Quantum Chemistry; Molecular Dynamics; Gd III ; kemisk fysik; Chemical Physics;

   Sammanfattning : The prime objectives of contrast agents in Magnetic Resonance Imaging(MRI) is to accelerate the relaxation rate of the solvent water protons in the surrounding tissue. Paramagnetic relaxation originates from dipole-dipole interactions between the nuclear spins and the fluctuating magnetic field induced by unpaired electrons. LÄS MER

3. 2. Combined Quantum Mechanical and Molecular Dynamics study of paramagnetic complexes : Towards an understanding of electronic spin relaxation

   Författare :Shehryar Khan; Michael Odelius; Jozef Kowalewski; Juha Vaara; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; molecular dynamics; quantum chemistry; zero-field splitting; kemisk fysik; Chemical Physics;

   Sammanfattning : The prime objectives of contrast agents in Magnetic Resonance Imaging (MRI) is to accelerate the relaxation rate of the solvent water protons in the surrounding tissue. Paramagnetic relaxation originates from dipole-dipole interactions between the nuclear spins and the fluctuating magnetic field induced by unpaired electrons. LÄS MER

4. 3. Photoelectron Spectroscopy on Atoms, Molecules and Clusters : The Geometric and Electronic Structure Studied by Synchrotron Radiation and Lasers

   Författare :Torbjörn Rander; Olle Björneholm; Gunnar Öhrwall; Maxim Tchaplyguine; Matthias Neeb; Uppsala universitet; []
   Nyckelord :Atomic and molecular physics; Free clusters; Electron spectroscopy; Doped clusters; Laser excitation; Alkali metals; Electronic structure; Geometric structure; X-ray photoelectron spectroscopy XPS ; Resonant Auger spectroscopy RAS ; Near-threshold x-ray absorption fine structure NEXAFS ; Ultraviolet photoelectron spectroscopy UPS ; Detuning; Ultra-fast dissociation UFD ; Sodium; Potassium; Oxygen; Bromomethane; Argon; Xenon; Krypton; Molecular field splitting; Core hole lifetime; Core excitation; Atom- och molekylfysik;

   Sammanfattning : Atoms, molecules and clusters all constitute building blocks of macroscopic matter. Therefore, understanding the electronic and geometrical properties of such systems is the key to understanding the properties of solid state objects. LÄS MER

5. 4. Nanospintronics with Molecular Magnets - Tunneling and Spin-Electric Coupling

   Författare :Javier Francisco Nossa Márquez; Fasta tillståndets fysik; []
   Nyckelord :Molecular magnets; spin exchange; spin-orbit interaction; magnetic anisotropy; spin frustration; spin chirality; spin-electric control; quantum transport; Coulomb blockade; density functional theory; quantum master equation.;

   Sammanfattning : This dissertation investigates theoretically electric control of the magnetic properties of molecular magnets. Two classes of magnetic molecules are considered. The first class consists of molecules that are spin frustrated. LÄS MER

7. 5. Stark Spectroscopy, Lifetimes and Coherence Effects in Diatomic Molecular Systems

   Författare :Annie Hansson; Peder Royen; Michel Herman; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; diatomic; dipole moment; Stark effect; lifetimes; transition moment; coherence effects; EIT; Autler-Townes; Chemical physics; Kemisk fysik;

   Sammanfattning : In this dissertation is exemplified how different laser based methods are applied in high-resolution spectroscopic studies of internal properties of diatomic molecules.A molecular beam apparatus assembly is described, where a laser ablation source is combined with a time-of-flight mass spectrometer. LÄS MER