Sökning: "Matthias Beller"

Hittade 4 avhandlingar innehållade orden Matthias Beller.

  1. 1. Artificial Water Splitting: Ruthenium Complexes for Water Oxidation

    Författare :Lele Duan; Licheng Sun; Matthias Beller; KTH; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; water oxidation; ruthenium; electrochemistry; DFT calculation; photoelectrochemistry; negatively charged ligand; catalyst;

    Sammanfattning : This thesis concerns the development and study of Ru-based water oxidation catalysts (WOCs) which are the essential components for solar energy conversion to fuels. The first chapter gives a general introduction about the field of homogenous water oxidation catalysis, including the catalytic mechanisms and the catalytic activities of some selected WOCs as well as the concerns of catalyst design. LÄS MER

  2. 2. Development of Biomimetic Catalytic Systems for Selective Oxidations with H2O2 and O2

    Författare :Mikael Johansson; Jan-Erling Bäckvall; Matthias Beller; Stockholms universitet; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; Biomimetic oxidations; catalyst immobilization; dihydroxylation; sulfoxidation; flavin; Chemistry; Kemi; Organic Chemistry; organisk kemi;

    Sammanfattning : Four different catalytic systems were studied for biomimetic coupled oxidations using H2O2 or O2. In the first example, osmium tetroxide works as a substrate-selective catalyst for dihydroxylation of olefins. Electron transfer to H2O2 is facilitated by electron transfer mediators (ETMs). LÄS MER

  3. 3. Selectivity in Palladium- and Enzyme-Catalyzed Reactions : Focusing on Enhancement of Reactivity

    Författare :Peter Nilsson; Anders Hallberg; Mats Larhed; Matthias Beller; Uppsala universitet; []
    Nyckelord :MEDICAL AND HEALTH SCIENCES; MEDICIN OCH HÄLSOVETENSKAP; MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Pharmaceutical chemistry; Palladium; Heck; PCR; Microwaves; Farmaceutisk kemi; Pharmaceutical chemistry; Farmaceutisk kemi;

    Sammanfattning : Catalysis has a profound impact on all living species on the earth. Nature’s catalysts, the enzymes, have the ability to selectively promote a specific bio-chemical transformation, given the required substrate. LÄS MER

  4. 4. Catalytic Stereoselective Formation of C–O, C–C and C–B Bonds : A Voyage from Asymmetric Reactions Enabled by Lipases to Stereoselective Palladium-Catalyzed Oxidative Transformations of Enallenes

    Författare :Bin Yang; Jan Bäckvall; Matthias Beller; Stockholms universitet; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Synthesis; Enzymatic kinetic resolution; Palladium; Allenes; Oxidative Transformations; Ruthenium; Organic Chemistry; organisk kemi;

    Sammanfattning : This thesis has been focused on enzymatic kinetic resolutions and stereoselective oxidative transformations of enallenes catalyzed by PdII.In the first part of the thesis, a detailed discussion on Candida antarctica lipase B (CALB)-catalyzed kinetic resolution (KR) of δ-functionalized alkan-2-acetates is shown. LÄS MER