Sökning: "Kinetic mechanism"

Visar resultat 1 - 5 av 255 avhandlingar innehållade orden Kinetic mechanism.

  1. 1. Isotopes as Mechanism Spies : Nucleophilic Bimolecular Substitution and Monoamine Oxidase B Catalysed Amine Oxidation Probed with Heavy Atom Kinetic Isotope Effects

    Författare :Susanna MacMillar; Olle Matsson; Anita Hussénius; Daniel M. Quinn; Uppsala universitet; []
    Nyckelord :Organic chemistry; nucleophilic bimolecular substitution SN2; kinetic isotope effects; precision conductometry; monoamine oxidase B MAO B; reaction mechanism; carbon 11C 14C kinetic isotope effect; ion pairing triple-ion formation; para-substituted benzyl chlorides; tetrabytylammonium cyanide; Organisk kemi;

    Sammanfattning : This thesis concerns the study of reaction mechanisms by means of kinetic isotope effects (KIEs). Studies of the nucleophilic bimolecular substitution (SN2) reaction had the dual purpose of improving our fundamental understanding of molecular reactivity and assessing the ability of kinetic isotope effects to serve as mechanistic tools. LÄS MER

  2. 2. BlueBellMouse. A Tool for Kinetic Model Development

    Författare :Raffaella Bellanca; Förbränningsfysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; combustion; HCCI; reduction; engine; kinetic; simulation; graphical user interface; GUI; optimization; chemical mechanism; Physics; Fysik; Fysicumarkivet A:2004:Bellanca;

    Sammanfattning : The simulation of physical phenomena occurring in chemical reactors requires the description of the kinetics involved in the underlying combustion process. Kinetic models are developed for this purpose. LÄS MER

  3. 3. Pea carbonic anhydrase : a kinetic study

    Författare :Inga-Maj Johansson; W. Richard Chegwidden; Umeå universitet; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Pisum sativum; carbonic anhydrase; kinetic studies; site-directed mutagenisis;

    Sammanfattning : The enzyme carbonic anhydrase (CA), catalysing the interconversion between CO2 and HCO3', has long been known to be present in plants as well as in animals. Several of the animal isozymes, but none of the plant CAs, have been extensively studied. LÄS MER

  4. 4. Homogeneous Ignition - Chemical Kinetic Studies for IC-Engine Applications

    Författare :Per Amnéus; Förbränningsfysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Skeletal mechanism; Mechanism reduction; n-heptane; iso-octane; formaldehyde; methane; Motors and propulsion systems; Motorer; framdrivningssystem; Physics; Fysik; Detailed chemistry; Kinetic calculations; Engine knock; Homogeneous charge compression ignition; HCCI; Fysicumarkivet A:2002:Amnéus;

    Sammanfattning : Calculations on a Homogeneous Charge Compression Ignition (HCCI) engine have been performed. Zero-dimensional models were used. The simplest model compressed the gas to auto-ignition, using temperature and pressure at a certain crank angle position obtained from engine experiments. LÄS MER

  5. 5. Adsorption of Metallic Ions onto Chitosan : Equilibrium and Kinetic Studies

    Författare :Martha Benavente; Joaquín Martínez; Olle Wahlberg; KTH; []
    Nyckelord :ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; Adsorption; biosorption; chitin; heavy metals; isotherm; kinetic models; mining; speciation; water treatment; Chemical engineering; Kemiteknik;

    Sammanfattning : Equilibrium isotherms and the adsorption kinetics of heavy metals onto chitosan were studied experimentally. Chitosan, a biopolymer produced from crustacean shells, has applications in various areas, particularly in drinking water and wastewater treatment due to its ability to remove metallic ions from solutions. LÄS MER