Sökning: "Karl Anker Jørgensen"

Hittade 2 avhandlingar innehållade orden Karl Anker Jørgensen.

  1. 1. Development and Studies of the Processes Involved in Minor Enantiomer Recycling

    Författare :Anna Laurell Nash; Christina Moberg; Karl Anker Jørgensen; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; asymmetric catalysis; biocatalysis; cyanohydrins; dual activation; Lewis acid; Lewis base; minor enantiomer recycling; recycling; titanium; Kemi; Chemistry;

    Sammanfattning : This thesis describes the development and rationalization of processes involved in a new methodology developed in our group, minor enantiomer recycling.The first part of the thesis addresses mechanistic studies of one of the reactions involved in minor enantiomer recycling, dual Lewis acid-Lewis base catalyzed acetylcyanation of aldehydes. LÄS MER

  2. 2. Asymmetric Hydrogenations using N, P - Ligated Iridium Complexes

    Författare :Alexander Paptchikhine; Pher G. Andersson; Karl Anker Jørgensen; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; asymmetric hydrogenation; iridium; birch; boronates; fluorine;

    Sammanfattning : The research described in this thesis focuses on the catalytic asymmetric hydrogenation of prochiral olefins using N, P – chelated iridium catalysts. This catalytic system is tolerant to a wide range of substrates and performs better than the well-known ruthenium- and rhodium-catalytic systems for substrates devoid of coordinating groups in proximity of the olefin. LÄS MER