Sökning: "Intramolecular"

Visar resultat 1 - 5 av 165 avhandlingar innehållade ordet Intramolecular.

  1. 1. Intramolecular Electronic Interactions in Photon Upconversion and Singlet Fission

    Författare :Fredrik Edhborg; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Singlet Fission; Photon Upconversion; Intramolecular; Excitation Energy Transfer; Solar Energy Conversion;

    Sammanfattning : The sun provides our planet with an abundance of energy in the form of solar light – a continuous stream of photons. Increasing our direct utilization of solar energy will constitute a necessary part in our ongoing replacement of fossil fuels with energy sources free from greenhouse gas emissions. LÄS MER

  2. 2. Tailing Charges on New Paths : Ultrafast intramolecular charge transfer in chromophores

    Författare :Belinda Pettersson Rimgard; Leif Hammarström; Oliver S. Wenger; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; intramolecular charge transfer; interligand electron transfer; electron transfer; proton transfer; concerted electron-proton transfer; Marcus inverted region; solvent; temperature; femtosecond spectroscopy; proton-coupled energy transfer; Chemistry with specialization in Physical Chemistry; Kemi med inriktning mot fysikalisk kemi;

    Sammanfattning : By tailing charges on their paths within a molecule, one can gain fundamental knowledge of their inherent reactivity. The charges, originally residing in their lowest energy configuration, can upon light absorption move across the system, or transfer in between them. LÄS MER

  3. 3. Intramolecular isotope analysis reveals plant ecophysiological signals covering multiple timescales

    Författare :Thomas Wieloch; Jürgen Schleucher; Mats Nilsson; Gerd Gleixner; Lisa Wingate; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NMR spectroscopy; tree ring; isotope ratio; isotope effect; intramolecular 13C 12C signal; carbon allocation; acclimation; plant performance; climate reconstruction; plant ecophysiology;

    Sammanfattning : Our societies' wellbeing relies on stable and healthy environments. However, our current lifestyles, growth-oriented economic policies and the population explosion are leading to potentially catastrophic degradation of ecosystems and progressive disruption of food chains. LÄS MER

  4. 4. Studies on the intramolecular Claisen condensation and related reactions

    Författare :Hans K. E. Leijonmarck; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic Chemistry; organisk kemi;

    Sammanfattning : Intramolecular Claisen or Claisen-like condensations of ß-acetoxy esters, amides or imides to ß-keto-5-lactones are described. Two compounds which can give either this reaction or the analogous reaction to y-lactone prefer to give the latter. LÄS MER

  5. 5. Intramolecular electron transfer in DNA and ruthenium(II) systems

    Författare :Johan Olofsson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; solvent relaxation; light switch effect; dppz; electron transfer and hydrogen bond;

    Sammanfattning : When ruthenium(II) complexes with heteroaromatic ligands absorb light, an electron is pushed from the metal ion out into one of the ligands, a process called metal-to-ligand-charge-transfer (MLCT). The resulting excited state can be used to initiate further electron transfer processes, or it can decay relatively slow back into the ground state with the emission of light. LÄS MER