Sökning: "Institutioner Vid Lth"

Visar resultat 21 - 25 av 712 avhandlingar innehållade orden Institutioner Vid Lth.

1. 21. A Catalytic and Mechanistic Investigation of Palladium-Phosphine Catalysed Aqueous Hydroxycarbonylation. Steric and Electronic Properties of the Ligands

   Författare :Adriana Ionescu; Kemiska institutionen; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Oorganisk kemi; Inorganic chemistry; Naturvetenskap; Natural science; Isomerisation of hydroxyalkenes; Mechanism; Regioselectivity; Steric and electronic properties; Hydroxycarbonylation of styrene; Water-soluble phosphines; Palladium; Aqueous catalysis;

   Sammanfattning : The steric and electronic properties of eight water-soluble phosphines (1-8) were investigated by different methods. Phosphines 1-6 were tested as ligands in palladium catalysed hydroxycarbonylation of styrene. LÄS MER

3. 22. Structure and Phase Stability of Polyelectrolyte-Macroion Solutions

   Författare :Marie Skepö; Kemiska institutionen; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Physical chemistry; Fysikalisk kemi; hydrophobicity; spatially distributed interaction sites; protein-polymer interaction; Monte Carlo Simulations; redissolution; phase separation; cluster; complex; Polyelectrolytes; macroions;

   Sammanfattning : Polyelectrolytes are polymers bearing ionisable groups, which, in polar solvents, can dissociate into charged polymer chains (polyelectrolytes) and small counterions. In aqueous solutions, polyelectrolytes interact strongly with other macroions and in particular they tend to associate with objects of opposite charge and form complexes. LÄS MER

4. 23. Reactions of Model and Anticancer Active Platinum(IV/II) Complexes - A Kinetic and Mechanistic Study

   Författare :Kelemu Lemma; Kemiska institutionen; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Model Pt II complexes; Anticancer active Pt IV compounds; Cisplatin; Rescue agents; L-Ascorbic acid; Thiol; Substitution; Kinetics and mechanism; Electron transfer; Inorganic chemistry; Oorganisk kemi;

   Sammanfattning : In this thesis reductions of model and anticancer active Pt(IV) complexes with thiols and ascorbic acid and substitution reactions of cisplatin and model Pt(II) complexes with S-donor nucleophiles (rescue agents) have been investigated using stopped-flow and UV/VIS spectrophotometry. Glutathione (GSH) reduction of the anticancer active Pt(IV) compounds t- and c-[PtCl4(cha)(NH3)] (cha = cyclohexylamine), t-[PtCl4(thiazole)(NH3)] and c-[PtCl4(NH3)2] at 25 oC was observed to be very fast. LÄS MER

5. 24. Model Systems for Metal - DNA Interactions. With a Focus on Anticancer Active Platinum(II) Complexes

   Författare :Anna Ericson; Kemiska institutionen; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; kinetics; DNA; poly d T ; guanine; 6-thioinosine-5 -monophosphate; 6-thio-2 -deoxyinosine; 4-thiouridine-5 -monophosphate; 4-thio-2 -deoxyuridine; palladium II ; Gold III ; platinum II ; mechanism; salt effect; activation parameters; Inorganic chemistry; Oorganisk kemi;

   Sammanfattning : Reactions of trans-dicyanodichloroaurate(III) trans-dibromodicyanoaurate(III), trans-diamminedichlorogold(III), cis-diammine(aqua)chloroplatinum(II), cis-ammineaqua-(cyclohexylamine)chloroplatinum(II), chloro(terpyridine)platinum(II) and chloro-(diethylenetriaminepalldium(II) with dimethyl sulfide, thionucleosides, thionucleotides and thione- and guanine-containing 17-mer oligonucleotides have been investigated by use of conventional and high-pressure stopped-flow spectrophotometry and HPLC technique as a function of ionic strength, pH, temperature and pressure in aqueous solutions. The mechanism and rate of oxidation of dimethyl sulfide by gold(III) complexes depends on the concentration of free halide. LÄS MER

7. 25. Application of Laser Techniques for Combustion Studies

   Författare :Marcus Aldén; Fysiska institutionen; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Keywords: Laser-induced fluorescence; Raman Spectroscopy; Coherent anti-Stokes Raman Scattering CARS ; flames; laserspectroscopy; dye laser; lidar; remote sensing; combustion; air pollution; radicals; optical multichannel analyzer.; Fysicumarkivet A:1983:Aldén;

   Sammanfattning : The aim for this work has been to increase the applicability of laser spectroscopy techniques for studies of combustion processes, both what regards in-flame experiments, exhaust-gas analysis and remote sensing of the atmosphere. Raman spectroscopy has been used for analysis of exhaust gases from flames, model fires of wood and for inflame measurements. LÄS MER