Sökning: "Imines"

Visar resultat 11 - 15 av 34 avhandlingar innehållade ordet Imines.

1. 11. Amino acid-catalyzed synthesis of amino acid derivatives : Application and semi-synthesis of Paclitaxel, Docetaxel and their derivatives

   Författare :Pawel Dziedzic; Armando Córdova; Stephen Hanessian; Stockholms universitet; []
   Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Organocatlysis; amino acids; syntesis; Taxol and Taxotere derivatives; Chemistry; Kemi; organisk kemi; Organic Chemistry;

   Sammanfattning : This thesis deals with different applications of organocatalysis, where amino acid derivatives and small peptides are applied as catalysts. First, the development of environmentally friendly aldol reactions, carried out in aqueous media is illustrated. The corresponding β-hydroxy ketones are formed with ee´s up to 99%. LÄS MER

3. 12. Investigations of New Biomimetic Transamination Systems and Inclusion Complexation with Cyclodextrins

   Författare :Anders Hjelmencrantz; Centrum för analys och syntes; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; stereochemis; bicyclooctanes.Transamination; complexation; cyclodextrins; proton transfer; hydride transfer; stereochemistry; Transamination; Organic chemistry; Organisk kemi;

   Sammanfattning : Two new transamination systems are described. The first example is a dibenzo[a,d]- cycloheptene containing system, designed to accomplish a [1,3]-hydride transfer. Several catalysts have been examined for this purpose. tris-Pentafluorophenyl borane was found to be the most efficient catalyst. LÄS MER

4. 13. Synthesis of Novel Chiral Bicyclic Ligands and their Application in Iridium-Catalyzed Reactions

   Författare :Anna Trifonova; Pher G. Andersson; Guy Lloyd-Jones; Uppsala universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; asymmetric catalysis; Diels-Alder reaction; transfer hydrogenation; hydrogenation; amino-oxazoline; phosphine-oxazoline; imine; olefin; Organisk kemi; Organic chemistry; Organisk kemi;

   Sammanfattning : The synthesis of 2-aza-norborane derivatives is presented. The use of these compounds in preparation of Ir catalysts for asymmetric hydrogenations is described. The evaluation and optimization of the catalysts as well as the mechanistic aspects of the catalytic process are discussed. LÄS MER

5. 14. Development and Applications of Molybdenum-Catalyzed Chemoselective Amide Reduction

   Författare :Tove Slagbrand; Hans Adolfsson; André Charette; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; hydrosilylation; reduction; reductive functionalization; catalysis; amides; enamines; chemoselective; organisk kemi; Organic Chemistry;

   Sammanfattning : This thesis covers the development of catalytic methodologies for the mild and chemoselective hydrosilylation of amides. The first part describes the investigation of the Mo(CO)6-catalyzed reduction of carboxamides. LÄS MER

7. 15. Development of New Synthetic Routes to Organoboronates by Catalytic Allylic Substitution and C-H bond Functionalization

   Författare :Vilhelm Olsson; Kálmán Szabó; Gary A. Molander; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Palladium; Iridium; Boron; Catalysis; Organic chemistry; Organisk kemi; organisk kemi; Organic Chemistry;

   Sammanfattning : This thesis describes the development of new catalytic methods for the synthesis and application of organometallic reagents, mainly focusing on allylboronic acid derivatives. Thus, palladium pincer-complex catalysis has been applied for extending the scope of palladiumcatalyzed borylation reactions in the synthesis of regio- and stereodefined functionalized allylboronic acid derivatives. LÄS MER