Avancerad sökning

Visar resultat 1 - 5 av 34 avhandlingar som matchar ovanstående sökkriterier.

  1. 1. Asymmetric Hydrogenations of Imines, Vinyl Fluorides, Enol Phosphinates and Other Alkenes Using N,P-Ligated Iridium Complexes

    Författare :Jarle Sidney Diesen; Pher G. Andersson; Kálmán J. Szabó; Uppsala universitet; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Organic chemistry; Catalysis; Asymmetric; Hydrogenations; Reductions; Alkenes; Imines; Vinyl fluorides; Enolphosphinates; Transition metal; Complexes; Iridium; Organisk kemi; Chemistry; Kemi;

    Sammanfattning : The research described in this thesis is directed toward the efficient, enantioselective synthesis of chiral products that have useful functionality. This goal was pursued through catalytic asymmetric hydrogenation, a reaction class that selectively introduces one or two stereocenters into a molecule in an atom-efficient step. LÄS MER

  2. 2. Mechanistic Studies on Ruthenium-Catalyzed Hydrogen Transfer Reactions

    Författare :Jenny B. Åberg; Jan-Erling Bäckvall; Charles P. Casey; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; mechanistic studies; catalysis; ruthenium; hydrogen transfer; racemization; transfer hydrogenation; alcohols; ketones; amines; imines; inner-sphere; outer-sphere; solvent cage effect; Organic chemistry; Organisk kemi; organisk kemi; Organic Chemistry;

    Sammanfattning : Mechanistic studies on three different ruthenium-based catalysts have been performed. The catalysts have in common that they have been employed in hydrogen transfer reactions involving alcohols and ketones, amines and imines or both. LÄS MER

  3. 3. Asymmetric Hydrogenations : Syntheses of Ligands and Expansion of Substrate Scope

    Författare :Pradeep Cheruku; Pher Andesson; Jay Siegel; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Catalysis; Asymmetric; Hydrogenations; Reductions; Olefins; Imines; Enol phosphinates; Transition metal; Complexes; Iridium; Enamines; Ruthenium; Ligands; Trifluoromethyl; Diphenylvinylphosphine oxides; Vinyl phosphonates; Chemistry; Kemi;

    Sammanfattning : Asymmetric hydrogenation has emerged as a versatile methodology to obtain a wide range of chiral precursors. This thesis focused on the synthesis of new chiral ligands and the expansion of the substrate scope of asymmetric hydrogenations. LÄS MER

  4. 4. Ruthenium-catalyzed hydrogen transfer involving amines and imines : Mechanistic studies and synthetic applications

    Författare :Joseph S M Samec; Jan-E Bäckvall; Jack R. Norton; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Organisk kemi;

    Sammanfattning : This thesis deals with ruthenium-catalyzed hydrogen transfer involving amines and imines and is divided into two parts. In Part 1 a mechanistic study has been performed. LÄS MER

  5. 5. New methods for the synthesis of N-heteroaromatics and imines

    Författare :Kenji Kopf; Belén Martín Matute; Joseph P. A. Harrity; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; heterocyclic; heteroaromatic; atropisomer; pyridine; pyrimidine; MOF; amine coupling; catalysis; benzannulation; organisk kemi; Organic Chemistry;

    Sammanfattning : This thesis is divided in four chapters, containing the work realised in two universities and has as the aim the synthesis of nitrogen-containing compounds. The first chapter describes the project realised at The University of Sheffield. LÄS MER