Sökning: "Hydrogen bond"

Visar resultat 11 - 15 av 222 avhandlingar innehållade orden Hydrogen bond.

  1. 11. An Infrared Study of Intermolecular Interactions in Gaseous Hydrogen Bonded Molecular Complexes

    Författare :René Wugt Larsen; Lunds universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; intermolecular potential energy surface; Physical chemistry; Fysikalisk kemi; synchrotron radiation; infrared absorption spectroscopy; intermolecular vibration; molecular complex; Intermolecular interactions; hydrogen bond;

    Sammanfattning : Intermolecular interactions are responsible for the deviations of gases from ideality, determine the three- dimensional structure and folding dynamics of biological molecules, and the binding of molecules to surfaces as in heterogeneous catalysis. The hydrogen bond is the most important intermolecular interaction. LÄS MER

  3. 12. Physiology of Caldicellulosiruptor saccharolyticus: a hydrogen cell factory

    Författare :Karin Willquist; Teknisk mikrobiologi; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; growth activation; hydrogen tolerance; hydrogen yields CO2 inhibition; physiology; enzyme kinetics; Caldicellulosiruptor saccharolyticus; biohydrogen; energy metabolism;

    Sammanfattning : A high substrate conversion efficiency is a prerequisite for an economically feasible biohydrogen production. Caldicellulosiruptor saccharolyticus is a strictly anaerobic extreme thermophilic bacterium that is able to convert the theoretical maximum of 4 mol/mol glucose to H2. LÄS MER

  4. 13. Hydrogen Bonding in Liquid Alcohols

    Författare :Per Sillrén; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Hydrogen Bonded Liquids; Physics of liquids; Diffraction; Monte Carlo Simulation; Alcohols; Neutron Scattering; EPSR;

    Sammanfattning : Hydrogen bonded (H-bonded) materials, such as water, alcohols, sugars, and even DNA, are extremely important for biology, as well as chemical industry. Alcohols are used as solvents in paints, in perfumes, as cleaners, anti-freezers, or as an alternative to petrol in combustion engines. LÄS MER

  5. 14. Symmetry in Asymmetric Catalysis and Hydrogen Bond-Based Self-Assembly : Synthesis and Investigations

    Författare :Yutang Li; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; asymmetric catalysis; bissalen; asymmetric ring opening; pseudo-Cs; hydrogen bonding; self-assembly; C3 symmety; trilactam; scXRD; solubility; epoxidation; rearrangement; Baeyer-Villiger reaction; transition state; DFT calculation; cyclodextrin; polyethylene glycol; amphiphilicity;

    Sammanfattning : The thesis elaborates on four different projects focusing on synthesizing symmetry-related molecules and investigating their performance as catalysts for asymmetric catalysis or as monomers for hydrogen bond-based self-assembly.Chapter 2 describes a new method to desymmetrize a meso-ligand. LÄS MER

  7. 15. Transition metal-catalysed hydrogen transfer processes for C-C and C-N bond formation : Synthetic studies and mechanistic investigations

    Författare :Agnieszka Bartoszewicz; Belen Martin-Matute; Martin Albrecht; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; hydrogen transfer; catalysis; transition metal; organisk kemi; Organic Chemistry;

    Sammanfattning : This thesis focusses on synthetic studies and mechanistic investigations into reactions involving hydrogen-transfer processes.In the first part, the development of an efficient method for the synthesis of β-hydroxy ketones (aldols) and β-amino ketones (Mannich products) from allylic alcohols and aldehydes is described. LÄS MER