Sökning: "HSQC"

Visar resultat 1 - 5 av 14 avhandlingar innehållade ordet HSQC.

  1. 1. Multivariate Analysis of 2D-NMR Spectroscopy : Applications in wood science and metabolomics

    Författare :Tommy Öman; Mattias Hedenström; Bjart Frode Lutnaes; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; 2D NMR; HSQC; cellulose; ligning; STOCSY; HSQC-STOCSY; crystallinity; biologisk kemi; biological chemistry;

    Sammanfattning : Wood is our most important renewable resource. We need better quality and quantity both according to the wood itself and the processes that are using wood as a raw material. Hence, the understanding of the chemical composition of the wood is of high importance. LÄS MER

  3. 2. Fundamental Aspects of Lignin Carbohydrate Complexes (LCC) : Mechanisms, Recalcitrance and Material concepts

    Författare :Nicola Giummarella; Martin Lawoko; Gunnar Henriksson; Arthur J. Ragauskas; KTH; []
    Nyckelord :LANTBRUKSVETENSKAPER; AGRICULTURAL SCIENCES; Lignin Carbohydrates Complexes; Phenyl Glycosides; Benzyl Ethers; Benzyl and γ-esters; Universal Mild Quantitative fractionation; LCC mechanism formation; Extracellular lignin; Dehydogenation polymer; Autohydrolysis; Recalcitrance; Acetylation role; HSQC; HMBC; HSQC-TOCSY; 13C; 31P NMR; Thioacidolysis-GC; SEC; Green; Biomimetic; One-pot-lignin functionalization; Lignin platform material.; Fiber- och polymervetenskap; Fibre and Polymer Science;

    Sammanfattning : Covalent bonds between lignin and carbohydrates, forming a matrix referred to as lignin carbohydrate complexes (LCC), remain one of the most controversial topics in wood chemistry. A key issue is whether they are formed during chemical and mechanical pretreatments of the compact wood structure or actually present in wood prior to isolation. LÄS MER

  4. 3. Glutaredoxin 3 from Escherichia coli : NMR structure analysis and structural aspects of the enzymatic mechanism

    Författare :Kerstin Nordstrand; Karolinska Institutet; Karolinska Institutet; []
    Nyckelord :;

    Sammanfattning : The structure of Escherichia coli glutaredoxin 3 (Grx3) was investigated using NMR spectroscopy in combination with isotope labeling. Nearly complete sequence specific assignment were obtained for the reduced Grx3 using a 15N enriched protein sample. LÄS MER

  5. 4. Protected Lignin Biorefining: Fundamental Insights on Lignin Reactivity

    Författare :Maria Karlsson; Martin Lawoko; Åsa Emmer; Olena Sevastyanova; John Ralph; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Sustainability; lignin; biorefinery; cyclic organosolv extraction; preserved structure; NMR; MALDI-TOF MS; Hållbarhet; lignin; bioraffinaderi; cyklisk organosolv extraktion; bevarad struktur; NMR; MALDI-TOF MS; Fiber- och polymervetenskap; Fibre and Polymer Science;

    Sammanfattning : The potential to utilize lignin, which constitutes as much as 15-30% of the biomass, needs further evaluation. In the transition towards a bioeconomy, lignin has the potential to replace fossil-based phenols. Attempts to valorize the available technical lignins are ongoing; however, that lignin suffers from molecular heterogeneity. LÄS MER

  7. 5. Conformations of Flexible Oligosaccharides : Molecular Simulations and NMR spectroscopy

    Författare :Robert Pendrill; Göran Widmalm; Jens Duus; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Carbohydrates; Oligosaccharide; Conformation; NMR spectroscopy; MD simulations; organisk kemi; Organic Chemistry;

    Sammanfattning : The conformational preferences of several oligosaccharides are investigated herein using a combination of NMR spectroscopy and molecular dynamics (MD) simulations, focusing on the torsion angles associated with the glycosidic linkages.Strategies for obtaining usable J-HMBC spectra for carbons with an adjacent 13C label are described. LÄS MER