Sökning: "Galvanic cell"

Visar resultat 1 - 5 av 7 avhandlingar innehållade orden Galvanic cell.

1. 1. Thermodynamic Studies of the Fe-Pt System and “FeO”-Containing Slags for Application Towards Ladle Refining

   Författare :Patrik Fredriksson; KTH; []
   Nyckelord :Thermodynamics; Activity; Galvanic cell; Calorimetry; Gas equilibration technique; Iron-platinum alloys; FeO; Slags; Modelling; Ladle;

   Sammanfattning : In the present work, the thermodynamic activites of ironoxide, denoted as "FeO" in the slag systems Al2O3-"FeO", CaO-"FeO", "FeO"-SiO2, Al2O3-"FeO"-SiO2, CaO-"FeO"-SiO2and "FeO"-MgO-SiO2were investigated by employing the gasequilibration technique at steelmaking temperatures. Thestrategy was to expose the molten slag mixtures kept inplatinum crucibles for an oxygen potential, determined by aCO/CO2-ratio. LÄS MER

3. 2. Thermodynamic investigations of transition metal systems containing coabon and nitrogen

   Författare :Lidong Teng; Seshadri Seetharaman; Tooru Matsumiya; KTH; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Materials science; thermodynamic activity; galvanic cell technique; transition metal carbides; transition metal nitrides; phase equilibrium; Materialvetenskap; Materials science; Teknisk materialvetenskap;

   Sammanfattning : In view of the important applications of carbides and carbo-nitrides of transition metals in the heat-resistant and hard materials industries, the thermodynamic activities of Cr and Mn in the Cr-C, Fe-Cr-C, Mn-Ni-C and Mn-Ni-C-N systems have been studied in the present work by the use of the galvanic cell technique. CaF2single crystals were used as the solid electrolyte. LÄS MER

4. 3. Thermodynamic Investigation of Co-Cr Alloys

   Författare :Thérèse Sterneland; KTH; []
   Nyckelord :Cobalt; chromium; experimental thermodynamics; solid state galvanic cell technique; differential scanning calorimetric technique DSC ; CALPHAD-technique; Thermo-Calc; phase diagram; experimental data;

   Sammanfattning : In a collaborative effort between the Divison of Metallurgyand the Divison of Computational Thermodynamics, RoyalInstitute of Technology (KTH), Stockholm, Sweden, experimentalinvestigations have been carried out in the binary Co-Crsystem. The experimental strategy has been to measure thethermodynamic activities of Cr by the solid oxide electrolytegalvanic cell technique, as well as to measure the molar heatcapacities of the alloys, as function of temperature, by theDSC technique. LÄS MER

5. 4. Thermodynamic Study of Co-Cr and C-Co-Cr Systems

   Författare :Therese Sterneland; Seshadri Seetharaman; K C Chou; KTH; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Cobalt; chromium; carbon; experimental thermodynamics; ; solid state galvanic cell technique; differential scanning examination; Metallurgical process engineering; Metallurgisk processteknik;

   Sammanfattning : An experimental investigation of the binary system Co-Cr and the ternary system C-Co-Cr has been carried out in the present thesis. The experimental strategy adopted for the binary system was to measure the thermodynamic activities of Cr, the molar heat capacity as function of time, the phase transformation temperatures with corresponding enthalpies, the Curie transition temperature as well as melting temperatures with corresponding enthalpies. LÄS MER

7. 5. Thermodynamic studies of some iron oxide-containing slag systems

   Författare :Patrik Fredriksson; KTH; []
   Nyckelord :;

   Sammanfattning : In the present investigation experimental measurements ofthe thermodynamic activities of iron oxide in the systems:Al2O3-“FeO”, CaO-“FeO”,“FeO”-SiO2 and, CaO-“FeO”-SiO2 wereperformed by using gas equilibration technique. Theexperimental measurements were performed in the temperaturerange 1823-1923 K for the binary systems and, at 1873 K for theternary system respectively. LÄS MER