Sökning: "Friedel-Crafts"

Visar resultat 1 - 5 av 6 avhandlingar innehållade ordet Friedel-Crafts.

  1. 1. C1 Building Blocks: New Approaches for Thiomethylations and Esterification

    Författare :Marcus Söderström; Luke R. Odell; Anders Karlén; Vittorio Pace; Uppsala universitet; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; NATURVETENSKAP; TEKNIK OCH TEKNOLOGIER; NATURAL SCIENCES; ENGINEERING AND TECHNOLOGY; Borontrifluoride; Dimethylsulfide; Thiomethylation; Methylthioethers; Dithioacetalation; Methyl-Dithioacetals; Friedel-Crafts; Diarylmethanes; Defluorination; Methyl-Dithioesters; Thioamides; Diazomethane; Esterification; Medicinal Chemistry; Läkemedelskemi; Medicinal Chemistry; Läkemedelskemi;

    Sammanfattning : The thioether motif is found in numerous pharmaceuticals. The simplest form of this motif, the methyl-thioether is similarly found in many biologically active compounds and has exhibited many advantageous properties. The installation of the thiomethyl moiety can be troublesome due to the toxicity and malodor of small sulfur reagents. LÄS MER

  3. 2. Development of highly enantioselective organocatalyzed transformations

    Författare :Palle Breistein; Armando Córdova; Mittuniversitetet; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Asymetric catalysis; aldehydes; proline derivatives; transition metals; Friedel-Crafts; conjugate addition; boration; α-alkylation;

    Sammanfattning : .... LÄS MER

  4. 3. Use of Aqueous Slurries of Oxides for Ecocompatible Organic Synthesis

    Författare :Zebastian Boström; Chalmers University of Technology; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : There is a continuous interest and need of developing environmentally benign synthetic routes. Increased public awareness and more rigid environmental legislation have elevated the drive towards sustainable development and ecocompatible syntheses. LÄS MER

  5. 4. Arene Iron Complexes in Organic Synthesis. New Routes to Benzophenones, Diaryl Selenides, Xanthones and Thioxanthones

    Författare :J Peter Storm; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Directed remote Metalation; nucleophilic aromatic addition; nucleophilic aromatic substitution; Arene-iron complexes; balanol; Organic chemistry; Organisk kemi;

    Sammanfattning : A multi-step route to unsymmetrically substituted benzophenones based on cationic hapto6-arene-hapto5-cyclopentadienyl iron complexes has been developed. The key features are nucleophilic aromatic substitution reactions performed on hapto6-2-chlorocarbomethoxybenzene-hapto5-cyclopentadienyl iron hexafluorophosphate with phenoxides, followed by intramolecular Friedel-Crafts ring-closure. LÄS MER

  7. 5. Sustainable porous organic materials : Synthesis, sorption properties and characterization

    Författare :Fredrik Björnerbäck; Niklas Hedin; Knut Irgum; Stockholms universitet; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; porous materials; sorbents; microporous; CO2 capture and separation; gas adsorption; activated carbon; humins; hypercrosslinked polymers; sustainable; Materials Chemistry; materialkemi;

    Sammanfattning : The resources available to us humans, including metals, minerals, biomass, air, water, and anything else on the planet, are being used at an increasing rate. This anthropogenic use of resources both depletes the resources and has negative impacts on other resources, e.g. the biosphere. LÄS MER