Sökning: "Enol phosphinates"

Hittade 2 avhandlingar innehållade orden Enol phosphinates.

  1. 1. Asymmetric Hydrogenations : Syntheses of Ligands and Expansion of Substrate Scope

    Författare :Pradeep Cheruku; Pher Andesson; Jay Siegel; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Catalysis; Asymmetric; Hydrogenations; Reductions; Olefins; Imines; Enol phosphinates; Transition metal; Complexes; Iridium; Enamines; Ruthenium; Ligands; Trifluoromethyl; Diphenylvinylphosphine oxides; Vinyl phosphonates; Chemistry; Kemi;

    Sammanfattning : Asymmetric hydrogenation has emerged as a versatile methodology to obtain a wide range of chiral precursors. This thesis focused on the synthesis of new chiral ligands and the expansion of the substrate scope of asymmetric hydrogenations. LÄS MER

  2. 2. Asymmetric Hydrogenations of Imines, Vinyl Fluorides, Enol Phosphinates and Other Alkenes Using N,P-Ligated Iridium Complexes

    Författare :Jarle Sidney Diesen; Pher G. Andersson; Kálmán J. Szabó; Uppsala universitet; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Organic chemistry; Catalysis; Asymmetric; Hydrogenations; Reductions; Alkenes; Imines; Vinyl fluorides; Enolphosphinates; Transition metal; Complexes; Iridium; Organisk kemi; Chemistry; Kemi;

    Sammanfattning : The research described in this thesis is directed toward the efficient, enantioselective synthesis of chiral products that have useful functionality. This goal was pursued through catalytic asymmetric hydrogenation, a reaction class that selectively introduces one or two stereocenters into a molecule in an atom-efficient step. LÄS MER