Sökning: "Donor-Acceptor Complexes"

Visar resultat 1 - 5 av 8 avhandlingar innehållade orden Donor-Acceptor Complexes.

  1. 1. Controlling Charge and Energy Transfer Processes in Artificial Photosynthesis : From Picosecond to Millisecond Dynamics

    Författare :Magnus Borgström; Leif Hammarström; Jan Davidsson; Sebastiano Campagna; Uppsala universitet; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Physical chemistry; Artificial photosynthesis; Electron transfer; Energy transfer; Ruthenium; Manganese; Charge-separated state; Donor-acceptor; Fysikalisk kemi; Physical chemistry; Fysikalisk kemi;

    Sammanfattning : This thesis describes an interdisciplinary project, where the aim is to mimic the initial reactions in photosynthesis. In photosynthesis, the absorption of light is followed by the formation of charge-separated states. The energy stored in these charge-separated states is further used for the oxidation of water and reduction of carbon dioxide. LÄS MER

  2. 2. Single and Accumulative Electron Transfer – Prerequisites for Artificial Photosynthesis

    Författare :Susanne Karlsson; Leif Hammarström; Hans-Christian Becker; Devens Gust; Uppsala universitet; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Artificial photosynthesis; Photoinduced charge separation; Electron transfer; Energy transfer; Accumulative electon transfer; Donor-acceptor; Ruthenium; Linear arrays; Chemical physics; Kemisk fysik; Kemi med inriktning mot kemisk fysik; Chemistry with specialization in Chemical Physics;

    Sammanfattning : Photoinduced electron transfer is involved in a number of photochemical and photobiological processes. One example of this is photosynthesis, where the absorption of sunlight leads to the formation of charge-separated states by electron transfer. LÄS MER

  3. 3. Atomic Scale Modelling in Photoelectrocatalysis : Towards the Development of Efficient Materials for Solar Fuel Production

    Författare :Giane B. Damas; Carlos Moyses Araujo; Rajeev Ahuja; Clas Persson; Uppsala universitet; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Photocatalytic hydrogen production; polymeric materials; donor-acceptor architecture; small molecules; density functional theory; hydrogen binding free energies; exciton binding energies; electrocatalysis; carbon dioxide conversion; formic acid production; Sn-based electrodes; Tin oxides; Ru-complexes; Metal Organic Frameworks; carbon dioxide capture.;

    Sammanfattning : Using sunlight to produce valuable chemicals has been pointed out as an interesting alternative to deal with the well-known environmental problem related to the use of fossil fuels for energy generation. Thus, it is crucial for this field the development of novel photocatalysts that could drive the uphill reactions with high efficiency while presenting low price and toxicity. LÄS MER

  4. 4. Dynamics of Excitation Transfer and Charge Separation in Polymeric Semiconductors

    Författare :Arvydas Ruseckas; Kemisk fysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Anisotropy; Photoinduced absorption; Femtosecond spectroscopy; Polythiophene; Conjugated polymers; Donor-Acceptor Complexes; Carbazole; Charge separation; Excitation transfer; Recombination; Physics; Fysik;

    Sammanfattning : Dynamics of optically excited electronic states have been studied in solid films and solutions of semiconducting polymers and model compounds. Transient absorption, monitored in the spectral range from 0.9 eV to 2.5 eV with a time resolution of about 100 fs, was the main experimental technique. LÄS MER

  5. 5. 31 P- and 65 Cu- solid state NMR studies of Cu(I) di-alkyl-dithiophosphates : complex Formation Mechanism on Synthetic Chalcocite Surfaces

    Författare :Daniela Rusanova; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Chemistry of Interfaces; Gränsytors kemi;

    Sammanfattning : Alkyl substituted derivatives of dithiophosphoric acid are frequently used as collectors in froth flotation enrichment of copper sulfide ores. Due to interaction between Cu atoms at the surface and thiol collector molecules, a concomitant adsorption process occurs on the mineral surface. LÄS MER