Sökning: "Cross-coupling"

Visar resultat 1 - 5 av 61 avhandlingar innehållade ordet Cross-coupling.

1. 1. Iron or Copper? - Method Development and Mechanistic Studies on Cross-Coupling Reactions

   Författare :Per-Fredrik Larsson; Göteborgs universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Iron; Copper; Transition metal; Cross-coupling; Reaction mechanism; Kinetic investigation; Hammett study; Sustainable catalysis; Trace-metal; Mass-transfer; Ligand development; Ligand scope;

   Sammanfattning : The area of catalysis has had an immeasurable impact on modern society. This has been acknowledged through several Nobel prizes during the 20th century ranging from Haber (1918) for the synthesis of ammonia to Richard F. Heck, Ei-ichi Negishi, and Akira Suzuki (2010) for palladium-catalyzed cross-coupling reactions. LÄS MER

3. 2. Copper- and nickel-catalyzed cross-coupling reactions : synthesis of 2-substituted 1,3-dienes and mechanistic and synthetic studies of the copper-mediated allylic substitution reaction

   Författare :A. Sofia E. Karlström; Alexandre Alexakis; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic Chemistry; organisk kemi;

   Sammanfattning : .... LÄS MER

4. 3. Olefins from carbonyls : Development of new phosphorus-based cross-coupling reactions

   Författare :Nicolas Daniele D'Imperio; Sascha Ott; Carlos Romero-Nieto; Uppsala universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; olefins; carbonyl olefination; phosphaalkenes; stereoselective synthesis; Wittig; Horner-Wadsworth-Emmons; McMurry;

   Sammanfattning : Olefins, compounds containing C=C double bonds, are omnipresent in nature and serve as useful starting materials for various chemical modifications. Olefins are of crucial importance in Medicinal Chemistry and are also present in essential objects like dyes, polymers and plastics. LÄS MER

5. 4. New Reactions with Allyl- and Allenylboron Reagents : Transition-Metal-Catalyzed and Transition-Metal-Free Carbon-Carbon Bond Formation Processes

   Författare :Dong Wang; Kálmán J. Szabó; Jianbo Wang; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; carbon-carbon bond formation; cross-coupling; organoboron compound; allylboron reagent; allylation; transition metal; metal carbene; allenylboron reagent; transition metal free; diazo compound; tosylhydrazone; quinone; organisk kemi; Organic Chemistry;

   Sammanfattning : Organoboron compounds have been widely used in carbon-carbon bond formation reactions in organic synthesis and catalysis. This thesis is focused on cross-coupling reactions of allyl-, allenylboronic acids and their ester derivatives via transition metal catalysis or transition-metal-free processes. LÄS MER

7. 5. Iron catalyzed C-C coupling reactions - mechanistic investigations

   Författare :Anna Hedström; Göteborgs universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; iron; homogenous catalysis; cross coupling; C-C bond formation; reaction mechanisms; kinetic investigations; competitive Hammett study; density functional theory;

   Sammanfattning : The mechanism of the iron catalyzed cross coupling of aryl electrophiles with alkyl Grignard reagents was studied. The reaction proceeds via a rate-limiting oxidative addition of the aryl halide to an Fe(I) complex generated in situ. A transmetalation from an aryl Grignard reagent occurs either before or after the oxidative addition. LÄS MER