Sökning: "Coordination chemistry"

Visar resultat 6 - 10 av 159 avhandlingar innehållade orden Coordination chemistry.

  1. 6. Responsive Molecular Systems through Dynamic Covalent Chemistry

    Författare :Antanas Karalius; Zoltan Szabo; Stefan Matile; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; stimuli-responsiveness; dynamic covalent reactions; systems chemistry; constitutional dynamics; non-equilibrium systems; nitroaldol reaction; dynamers; reversible polymerization; boronate ester; imine ligand; metal coordination; self–assembly; emergent properties; network topology.; stimuli-responsivitet; dynamiska kovalenta reaktioner; systemkemi; konstitutionell dynamik; icke-jämviktssystem; nitroaldolreaktion; dynamerer; reversibel polymerisation; boronester; iminligand; metallkoordination; själv-organisation; emergenta egenskaper; nätverkstopologi.; Kemi; Chemistry;

    Sammanfattning : Nature tends to inspire research in chemistry. Systems that emerge from molecules interacting via reaction networks is something that life has mastered over the course of evolution in order to produce complexity. Dynamic reactions are key in systems chemistry, where reaction networks give rise to complex, emergent behavior. LÄS MER

  3. 7. Imidazole containing polymers complexed with Cu2+ and Zn2+

    Författare :Markus Andersson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; vibrational spectroscopy; far-FTIR; EPR; cross-linking; DSC; Coordinating polymer; imidazole; mid-FTIR; metal ion;

    Sammanfattning : An enormous problem for the shipping industry is fouling of marine organisms such as algae andbarnacles on the boat hull. The negative consequences for the society are both economical as well asenvironmental. To prevent fouling in general, biocides are typically incorporated directly into the paint. LÄS MER

  4. 8. Synthesis and Photophysical Characterization of Annihilator-Sensitizer Pairs for Triplet-Triplet Annihilation Based Photon Upconversion

    Författare :Victor Gray; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Triplet-Triplet Annihilation; Photon Upconversion; Anthracene;

    Sammanfattning : Transitioning to a future society, independent of fossil fuels, will denitely require the use of solar radiation for power and fuel production. Due to energy mismatch betweendevice absorption and the broad band irradiation provided by the sun there are severe limitations to how efficient devices for direct conversion of solar radiation can be. LÄS MER

  5. 9. Coordination chemistry of late transition metals with PCP ligands. Synthesis, catalysis and mechanism

    Författare :Daniel Olsson; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; Organometallic chemistry; Metallorganisk kemi; Organic chemistry; Oorganisk kemi; Inorganic chemistry; Suzuki reaction; Stille reaction; catalysis; cyclometalation; C-H activation; PCP complex; POCOP ligand; PCP ligand; iridium; palladium; platinum;

    Sammanfattning : Abstract The work presented in this thesis discusses synthesis of PCP-complexes and utilisations of such organometallic compounds in catalysis. The complexes, obtained by intramolecular Csp3-H activation, are based on the metals palladium, platinum and iridium. LÄS MER

  7. 10. Metals in Dynamic Chemistry: Selection & Catalysis

    Författare :Brian J.J. Timmer; Olof Ramström; Stéphane Bellemin-Laponnaz; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; constitutional dynamic chemistry; selection; multivalent interactions; carbohydrates; quartz crystal microbalance; catalyst screening; aqueous olefin metathesis; C-H activation; Kemi; Chemistry;

    Sammanfattning : In the adaptation to the oxidative environment on earth, metals played a crucial role for the evolution of life. The presence of metals also allowed access to advanced functions due to their unique coordination sphere and reactivity. LÄS MER