Sökning: "Cl2"

Visar resultat 1 - 5 av 20 avhandlingar innehållade ordet Cl2.

  1. 1. Molecular beam study of non-adiabatic electron transfer in the Cl2+Ksurf surface reaction

    Författare :Lars Hellberg; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; harpooning; electron transfer; Cl2; surface; exo-electrons; sticking; halogen; non-adiabatic; chemiluminescence;

    Sammanfattning : Halogen molecules impinging on alkali metal surfaces constitute model systems for studies of charge transfer, dissociation dynamics and non-adiabatic energy dissipation in molecule-surface reactions. This thesis reports emission of exo-electrons and photons from the surface as a result of strong non-adabaticity in the Cl2 gas on K$^{solid}$ reaction. LÄS MER

  3. 2. Structure and Dynamics of Core-Excited Species

    Författare :Oksana Travnikova; Maria Novella Piancastelli; Svante Svensson; Denis Ceolin; Pascal Lablanqui; Uppsala universitet; []
    Nyckelord :Physics; Synchrotron radiation; X-ray Photoelectron Spectroscopy XPS ; X-ray Absorption Spectroscopy XAS ; Resonant Auger Spectroscopy RAS ; Auger Electron Spectroscopy AES ; Energy-Selected Auger Electron PhotoIon COincidence ES-AEPICO ; core excitation; core ionization; linear free energy relationships LFER ; molecular-field splitting; substituent effects; nuclear dynamics; isomerization; Cl2; N2O; methane derivatives; allene; acetylacetone; Fysik;

    Sammanfattning : In this thesis we have performed core-electron spectroscopy studies of gas phase molecular systems starting with smaller diatomic, continuing with triatomic and extending our research to more complex polyatomic ones. We can subdivide the results presented here into two categories: the first one focusing on electronic fine structure and effect of the chemical bonds on molecular core-levels and the other one dealing with nuclear dynamics induced by creation of a core hole. LÄS MER

  4. 3. Le développement d'aspects phonético-phonologiques du français chez des enfants bilingues simultanés et successifs : Le VOT et la liaison dans une étude de cas multiples

    Författare :Frida Splendido; Svenska som främmande språk; []
    Nyckelord :HUMANIORA; HUMANITIES; French; language acquisition; phonology; L2; L1; 2L1; development; VOT; liaison; critical period hypothesis; bilingualism; child L2;

    Sammanfattning : This dissertation describes the development of Voice Onset Time (VOT) and liaison in child second language (cL2) French (L1: Swedish) as compared to simultaneous Swedish-French bilinguals (2L1) and monolingual (1L1) French children. VOT is studied in both languages but liaison only exists in French. LÄS MER

  5. 4. Degradation of polyethylene pipes distributing chlorinated water : depletion of stabilizers, release of degraded products and polymer degradation

    Författare :Wenbin Yu; Ulf Gedde; Mats Jonsson; Minna Hakkarainen; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; polyethylene pipes; chlorine dioxide; degradation; Polymer chemistry; Polymerkemi;

    Sammanfattning : This thesis presents the study of antioxidants depletions in chlorinated media (10 ppm Cl2 - and ClO2 - aqueous media), polyethylene pipes degradations scenarios and migration of the degraded species to aqueous phase. Pressure testing on pipes and squalane testing with controlled pH aqueous media (6.8 ± 0. LÄS MER

  7. 5. Deterioration of Polyethylene Exposed to Chlorinated Species in Aqueous Phases : Test Methods, Antioxidants Consumption and Polymer Degradation

    Författare :Wenbin Yu; Ulf Gedde; Sahar Al-Malaika; KTH; []
    Nyckelord :Antioxidants; Polyethylene pipes; Chlorine dioxide; Degradation;

    Sammanfattning : This thesis presents a study of antioxidant depletion in water containing chlorinated species (water containing 10 ppm either Cl2 or ClO2, buffered to pH = 6.8), the degradation products in the aqueous phase, and polyethylene pipe degradation scenarios. LÄS MER