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Visar resultat 1 - 5 av 15 avhandlingar som matchar ovanstående sökkriterier.

  1. 1. Near field immobilization of selenium oxyanions

    Författare :Anders Puranen; Mats Jonsson; Christophe Jegou; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Se-79; Selenium; Immobilization; Redox; Iron; Corrosion; Palladium; Catalyst; Spent Nuclear Fuel; Repository; Nuclear chemistry; Kärnkemi;

    Sammanfattning : The topic of this doctoral thesis is the potential near field immobilization of the radionuclide 79Se after intrusion of groundwater into a spent nuclear fuel canister in a repository. 79Se is a non naturally occurring long lived selenium isotope formed as a result of fission in nuclear fuel. LÄS MER

  2. 2. Immobilizing catalysts on textiles : case of zerovalent iron and glucose oxidase enzyme

    Författare :Mohammad Neaz Morshed; Vincent Nierstrasz; Frank Hollmann; Högskolan i Borås; []
    Nyckelord :Biocatalysts; Catalyst immobilization; Catalytic reduction; Chitosan; Dye removal; Environmental remediation; Enzyme immobilization; Glucose oxidase; Hyperbranched dendrimers; Heterogeneous catalysis; Heterogeneous bio-Fenton; Heterogeneous Fenton; Inorganic catalysts; Phenol removal; Polyester nonwoven fabric; Pathogenic bacteria removal; Plasma ecotechnology; Polyethylenimine; Textile catalyst; Textile biotechnology; Textile surface modification; Wastewater treatment; Zerovalent iron; 生物催化剂; 涤纶无纺布; 金属颗粒:铁固定化; 超支化树状大分子; 聚酰胺胺树状大分子 3-氨基丙基); 三乙氧基硅烷; 1-硫代甘油; 聚乙烯胺; 壳聚糖; 葡萄糖氧化酶; 氧化还原酶; 酶固定化,物理吸附; 纤维催化剂; 多相催化; 抗菌纺织品; 革兰氏阳性(G ve)菌 革兰氏阴性(G-ve)菌; 类芬顿; 生物芬顿; 染料去除; 苯酚去除; 生物催化; 产业纺织品; 纺织生物技术; 纺织品表面改性; 环境治理; 废水处理; 零价铁。; Biocatalyseurs; Immobilisation de catalyseurs; Reduction de catalyseurs; Chitosane; Élimination de colorants; Assainissement de l’environnement; Immobilisation d’enzymes; Glucose oxydase; Dendrimères hyper-ramifiés; Catalyse hétérogène; Bio-Fenton hétérogène; Fenton hétérogène; Catalyseurs inorganiques; Élimination de phénols; Non-tissé Polyester; Élimination de bactéries pathogènes; Écotechnologie plasma; Polyéthylèneimine; Catalyseur textile; Biotechnologie textile; Modification de surface textile; Traitement des eaux usées; Fer zéro-valent; Biokatalysatorer; Katalysatorimmobilisering; Katalytisk reduktion; Kitosan; Avlägsnande av färgämnen; Miljösanering; Enzymimmobilisering; Glukosoxidas; Hypergrenade dendrimerer; Heterogen katalys; Heterogen bio-Fenton; Heterogen Fenton; Oorganiska katalysatorer; Fenolavlägsnande; Polyester fiberduk; Avlägsnande av patogena bakterier; Plasmaekoteknik; Polyetylenimin; Textil katalysator; Textil bioteknik; Modifiering av textilytor; Avloppsrening; Zerovalent järn; Textil och mode generell ; Textiles and Fashion General ;

    Sammanfattning : Catalytic systems are one of the most effective technologies of modern chemical processes. The system uses a molecule called ‘catalyst’ that is capable of catalyzing a reaction without being produced or consumed during the process. LÄS MER

  3. 3. Flavins as Biomimetic Catalysts for Sulfoxidation by H2O2 : Catalyst Immobilization in Ionic Liquid for H2O2 Oxidations

    Författare :Auri Lindén; Jan-Erling Bäckvall; Peter Somfai; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; biomimetic; oxidation; catalysis; ionic liquid; hydrogen peroxide; Organic chemistry; Organisk kemi;

    Sammanfattning : This thesis deals with the development of catalytic oxidation reactions utilizing hydrogen peroxide as terminal oxidant. The main focus has been to find flavin catalysts that are easy to handle and stable to store but still able to perform the desired reaction. LÄS MER

  4. 4. Mononuclear Ruthenium Complexes that Catalyze Water to Dioxgen Oxidation

    Författare :Lianpeng Tong; Licheng Sun; Randolph Thummel; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Ruthenium complex; Homogeneous catalysis; Water oxidation; O2 evolution; anionic ligand; Molecular catalyst; Electrocatalysis; Kinetics; Artificial photosynthesis; Light-driven; Immobilization of catalyst;

    Sammanfattning : The theme of this thesis is the development of mononuclear Ru-based complexes that are capable of catalyzing the water oxidation (or O2-evolving) reaction, e.g. 2 H2O → O2 + 4 H+ + 4 e−. Several families of mononuclear Ru water oxidation catalysts were designed and prepared. LÄS MER

  5. 5. Development of Biomimetic Catalytic Systems for Selective Oxidations with H2O2 and O2

    Författare :Mikael Johansson; Jan-Erling Bäckvall; Matthias Beller; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Biomimetic oxidations; catalyst immobilization; dihydroxylation; sulfoxidation; flavin; Chemistry; Kemi; Organic Chemistry; organisk kemi;

    Sammanfattning : Four different catalytic systems were studied for biomimetic coupled oxidations using H2O2 or O2. In the first example, osmium tetroxide works as a substrate-selective catalyst for dihydroxylation of olefins. Electron transfer to H2O2 is facilitated by electron transfer mediators (ETMs). LÄS MER