Sökning: "C-C bond formation"

Visar resultat 11 - 14 av 14 avhandlingar innehållade orden C-C bond formation.

  1. 11. Chemical vapour deposition of boron-carbon thin films from organoboron precursors

    Författare :Maiwulidan (Mewlude) Yimamu (Imam); Henrik Pedersen; Jens Birch; Carina Höglund; Erik Lindahl; Linköpings universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : Boron-carbon (BxC) thin films enriched in 10B are potential neutron converting layers for 10Bbased solid-state neutron detectors given the good neutron absorption cross-section of 10B atoms in the thin film. Chemical Vapour Deposition (CVD) of such films faces the challenge that the maximum temperature tolerated by the aluminium substrate is 660 °C and low temperature CVD routes for BxC films are thus needed. LÄS MER

  3. 12. Studies of partial oxidation and combustion over heterogeneous catalysis by transient experiments

    Författare :Andreas Hinz; Avdelningen för kemiteknik; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Catalytic combustion; Selective Oxidation; Sulphur dioxide; Ammonia; Methanol; Propane; Metal catalysts; Metal oxide catalysts; Transients; Simulation; Chemical technology and engineering; Kemiteknik och kemisk teknologi; Carbochemistry; petrochemistry; fuels and explosives technology; Petrokemi; bränslen; sprängämnen;

    Sammanfattning : Transient experiments are one of many techniques available to study heterogeneous catalysis and the catalysts used. The results obtained by transient experiments contain valuable information that is helpful in explaining reaction mechanism and interaction at the catalytic surface. LÄS MER

  4. 13. Accuracy of mRNA Translation in Bacterial Protein Synthesis

    Författare :Jingji Zhang; Måns Ehrenberg; Olke C. Uhlenbeck; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; protein synthesis; genetic code; misreading; error hot spots; kinetics; aminoglycoside; Biokemi; Biochemistry;

    Sammanfattning : Reading of messenger RNA (mRNA) by aminoacyl-tRNAs (aa-tRNAs) on the ribosomes in the bacterial cell occurs with high accuracy. It follows from the physical chemistry of enzymatic reactions that there must be a trade-off between rate and accuracy of initial tRNA selection in protein synthesis: when the current accuracy, the A-value, approaches its maximal possible value, the d-value, the kinetic efficiency of the reaction approaches zero. LÄS MER

  5. 14. CVD Chemistry of Organoborons for Boron-Carbon Thin Film Depositions

    Författare :Mewlude Imam; Henrik Pedersen; Jens Birch; Marrku Leskelä; Linköpings universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : Boron-carbon thin films enriched with 10B are potential neutron converting layers for 10B-based solid state neutron detectors given the good neutron absorption cross section of 10B atoms in thin films. The common neutron-transparent base material, Al (melting point 660 °C), limits the deposition temperature and the use of chlorinated precursors forming corrosive by-products such as HCl. LÄS MER