Sökning: "Born-Oppenheimer approximation"
Visar resultat 1 - 5 av 10 avhandlingar innehållade orden Born-Oppenheimer approximation.
1. Four-Body Treatment of the Hydrogen-Antihydrogen System
Sammanfattning : This thesis presents a nonadiabatic (4-body) description of the hydrogen-antihydrogen system at a nonrelativistic level. The properties of the system, the rearrangement processes and the possible existence of resonance states are investigated by using a variational method for coupled arrangement channels, the Gaussian Expansion Method, and the stabilization method. LÄS MER
2. Photoelectron Spectroscopy on HCl and DCl : Synchrotron Radiation Based Studies of Dissociation Dynamics
Sammanfattning : Dissociation dynamics of the ionized molecules HCl and the deuterated system DCl has been studied in gas-phase using synchrotron based photoelectron spectroscopy (PES).The inner-valence "(4σ)-1" photoionization band for DCl and HCl was recorded using maximum resolution in order to probe an interference pattern between a dissociative and a bound electronic state. LÄS MER
3. Non-linear Spectroscopy of Conical Intersections
Sammanfattning : Conical Intersections (CIs) in a molecule originate from the breakdown of the Born-Oppenheimer approximation when electronic states come close in energy. Ultrafast non-radiative decay channels open up in the vicinity of a CI, thus funneling a molecule from one electronic state to another. LÄS MER
4. Complexity and Error Analysis of Numerical Methods for Wireless Channels, SDE, Random Variables and Quantum Mechanics
Sammanfattning : This thesis consists of the four papers which consider different aspects of stochastic process modeling, error analysis, and minimization of computational cost. In Paper I, we construct a Multipath Fading Channel (MFC) model for wireless channels with noise introduced through scatterers flipping on and off. LÄS MER
5. Theoretical studies of collisions involving the H2 reaction complex
Sammanfattning : In this thesis, collisions involving the H2 reaction complex are studied theoretically and the processes considered are mutual neutralization, double charge transfer, associative ionization, dissociative recombination and resonant ion-pair formation. These processes are examples of reactions that involve several excited states and where the Born-Oppenheimer approximation is not applicable. LÄS MER