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1. 1. Chiral building blocks for synthesis of pine sawfly sex pheromones Enantioselective Lipase Catalysed Acylations and Esterifications of Primary Alcohols and Acids and Synthesis of the Sex Pheromone of the Pine Sawfly Microdiprion pallipes

   Författare :Ba-Vu Nguyen; KTH; []
   Nyckelord :lipase; Pseudomonas cepacia; Candida rugosa; enantioselective; enantiomeric ratio; primary 2-methylalcohol; substituted-methylcarboxylic acid; pine sawfly; Microdiprion pallipes; sex pheromone; 3; 7; 11-trimethyl-2-tridecanol; stereoisomer;

   Sammanfattning : This thesis describes the development of new methods for thepreparation of enantiomerically pure methyl branched alkylcompounds and their use as building blocks in the synthesis ofstereoisomerically pure pheromones of pine sawflies.The high regioselectivity, enantioselectivity and activityof lipases in organic solvent in conjunction withenvironmentally compatible reaction conditions have madelipase-catalysed synthesis an attractive alternative toconventional synthetic methods in organic chemistry. LÄS MER