Sökning: "Aliphatic amines"

Visar resultat 1 - 5 av 18 avhandlingar innehållade orden Aliphatic amines.

  1. 1. Isocyanates, Amines and Alkanolamines : Sampling, Chromatography and Detection

    Författare :Jakob B. Riddar; Marianne Dalene; Gunnar Skarping; Daniel Karlsson; Håkan Westberg; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Air-sampling; Isocyanates; Aromatic amines; Aliphatic amines; Alkanolamines; Hydrophilic Interaction Liquid Chromatography; Dry Denuder-Filter sampler; Liquid Chromatography–tandem Mass Spectrometry; Polyurethane Foam Extraction; Analytical Chemistry; analytisk kemi;

    Sammanfattning : Isocyanates, aromatic-, aliphatic- and alkanolamines are commonly used in the industry today. Millions of workers in Europe are exposed. The most frequent health symptoms are respiratory and dermal disorder. Due to the health risk most of the compounds in this thesis are regulated by authorities and have occupational exposure limits (OELs). LÄS MER

  3. 2. Airborne Isocyanates, Aminoisocyanates and Amines

    Författare :Daniel Karlsson; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Environmental health; Miljökemi; Environmental chemistry; amines; aminoisocyanates; isocyanates; polyurethane; exposure; occupational; thermal degradation; chemiluminescence; mass spectrometry; Liquid chromatography; gas chromatography; Miljömedicin; Occupational health; industrial medicine; Yrkesmedicin; arbetsmiljömedicin;

    Sammanfattning : Isocyanates are used in the production of polyurethane (PUR). Exposure to isocyanates is associated with respiratory disorders and may occur during production or processing of PUR. During thermal degradation of PUR, amines and aminoisocyanates are formed in addition to isocyanates. LÄS MER

  4. 3. Transition Metal-Free O-, N- and S-Arylations with Diaryliodonium Salts

    Författare :Gabriella Kervefors; Berit Olofsson; Boris Nachtsheim; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Amines; hypervalent iodine; electrophilic arylation; methodology development; total synthesis; organisk kemi; Organic Chemistry;

    Sammanfattning : This thesis concerns the development of metal-free arylation procedures using diaryliodonium salts, a non-toxic and versatile electrophilic arylating reagent, with applications to synthesize biologically relevant targets.The first part describes a transition metal-free formal synthesis of phenoxazine with an O-functionalization of a certain phenol as a key step. LÄS MER

  5. 4. Photoinitiated Radical Carbonylation Using [11C]Carbon Monoxide : 11C-Labelling of Aliphatic Carboxylic Acids, Esters, and Amides

    Författare :Oleksiy Itsenko; Bengt Långström; Tor Kihlberg; Chryssostomos Chatgilialoglu; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; 11C-labelling; radicals; carbonylation; carbon monoxide; solvent effects; sensitizers; sulfoxides; WAY-100635; PET; Organisk kemi; Organic chemistry; Organisk kemi;

    Sammanfattning : One-step photoinitiated free radical carbonylation was employed for the rapid (5–7 min) labelling of aliphatic carboxylic acids, esters, and amides with a short-lived positron emitter 11C (t½ = 20.3 min) at the carbonyl position. The labelled compounds were synthesized from alkyl iodides (0.05–0. LÄS MER

  7. 5. Catalytic Hydrosilylation of Amides

    Författare :Alexey Volkov; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES;

    Sammanfattning : In this thesis, different protocols and approaches are described for thehydrosilylation of tertiary amides to amines or enamines. The development of simple andeffective methods for the production of amines from amides is of great importance to bothacademic and industrial users, since the final product represents a valuable building blockfor fine and bulk chemicals. LÄS MER