Sökning: "2D NMR"

Visar resultat 6 - 10 av 25 avhandlingar innehållade orden 2D NMR.

1. 6. Functional and Modular As=C and P=C Group Motifs

   Författare :Daniel Morales Salazar; Andreas Orthaber; Jose Goicoechea; Uppsala universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; materials; physical chemistry; arsaalkenes; phosphaalkenes; DBU; fluorene; photochemistry; arsenic; phosphorus; carbon; hydrogen; sulfur; gold; copper; organic materials; organic electronics; molecular electronics; polymers; transition metal complexes; molecular materials; small molecule; hydrogen bonding; electrochemistry; cyclic voltammetry; chronoamperometry; electropolymerization; artificial intelligence; potentiodynamic; modularity; functionality; XPS; DFT; π-conjugation effects; 2D-NMR; disilenes; siliconoids; group motifs; functional group; emergence; reactivity; reactive systems; organometallic complexes; π-delocalization; low-coordinate; main group chemistry; heavy p-block elements; pnictogens; copper I complex; gold I complex; photosensitizer; XRD; spectroelectrochemistry; electrochromism; smart materials; synthesis; phosphaalkene ligands; imine ligands; hysteresis-like criteria; representative settings; optimal criteria; transient covalence; interactive image; conformer; isomer; ligand scrambling; nanomaterials; stimuli-responsive; optical properties; ligand design; molecular design; X-ray crystallography; emission; self-assembly; As=C; Si=Si; P=C; multiple bond; equilibrium; heteroalkenes; alkenes; reversibility; Raman; ATR-FTIR; ERDA; Kemi; Chemistry;

   Sammanfattning : This work focuses on the design, synthesis, characterization, and application projections of low-coordinated heavy pnictogen-containing (described by the generic letter E, hence E=C) phosphaalkenes (P=C) and arsaalkenes (As=C), with emphasis on the E=C group motifs. The work aims to understand their functional and modular character, reactivity, and potential applications by stabilizing, isolating, and characterizing these species in low-coordination environments. LÄS MER

3. 7. Concentrated DNA-amphiphiles Structure, Hydration, and Dynamics

   Författare :Cecilia Leal; Fysikalisk kemi; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; amphiphiles; DNA; Physical chemistry; diffusion NMR; solid-state NMR; electrostatics; dynamics; local order; Fysikalisk kemi; hydration;

   Sammanfattning : The structure, hydration, and dynamics of concentrated DNA-amphiphile complexes were investigated by small-angle X-ray diffraction, sorption calorimetry, and nuclear magnetic resonance. A concentrated, electroneutral, DNA-amphiphile complex can be formed by mixing charge-stoichiometric solutions. LÄS MER

4. 8. Helicobacter pylori outer membrane vesicles and the host-pathogen interaction

   Författare :Annelie Olofsson; Anna Arnqvist; Mikael Rhen; Umeå universitet; []
   Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; H. pylori; outer membrane vesicles; 2D 31P; 1H COSY NMR; phospholipids; OMV proteome; adherence; endocytosis; CagA; OMV-host cell responses; yttermembran vesiklar;

   Sammanfattning : .... LÄS MER

5. 9. Spectroscopic data and multivariate analysis : tools to study genetic perturbations in poplar trees

   Författare :Susanne Wiklund; Ulf Edlund; Olav Kvalheim; Umeå universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NMR spectroscopy; Metabolomics; Degree of methylation; S-plot; SUS-plot; Metabonomics; Poplar; MLR; PLS; OPLS; PCA; Pectin; Wood; Organic chemistry; Organisk kemi;

   Sammanfattning : In our society in the 21st century one of the greatest challenges is to provide raw materials to the industry in a sustainable way. This requires increased use of renewable raw materials such as wood. Wood is widely used in pulp, paper and textile industries and ongoing research efforts aim to extend the use of wood in e.g. LÄS MER

7. 10. Nano-particulate Silica Hydrogels Imaged in 2D and 3D using TEM: Effects of local pore structure on mass transport and applications in aggregation dynamics

   Författare :Charlotte Hamngren Blomqvist; Chalmers tekniska högskola; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; silica gel; colloidal silica gel; interconnectivity; nanoporous; electron tomography; silica nanoparticle gel; mass transport; nanostructure; accessible volume fraction; 3D structure;

   Sammanfattning : Porous materials are frequently used in everyday applications including food science, pharmaceuticals, fuel cell membranes, batteries and solar cells. A key aspect in these porous materials is how their micro- and nano-structure affect the internal transport of for example water, particles or charges. The transport is a three-dimensional process. LÄS MER