Sökning: "2-bis"

Visar resultat 1 - 5 av 41 avhandlingar innehållade ordet 2-bis.

1. 1. Synthesis and characterization of dendritic macromolecules based on 2,2-bis(hydroxymethyl)propionic acid

   Författare :Henrik Ihre; KTH; []
   Nyckelord :;

   Sammanfattning : Dendrimers are a relatively new type of macromolecules characterized by a well-defined, highly branthed, layered structure with a multitude of chain ends, adopting a globular shape at higher molar masses. Dendrimers are usually constructed from ABx type of monomers in either one of the two step-wise approaches known as thedivergentor theconvergent growth approach. LÄS MER

3. 2. Dendrimers and dendronized polymers : synthesis and characterization

   Författare :Andreas Nyström; Anders Hult; A. Dieter Schlüter; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Dendrimers; dendronized polymers; atom transfer radical polymerisation; ring-opening metathesis polymerization; reversible addition-fragmentation chain transfer polymerization; 2; 2-bis methylol propionic acid; tri-block copolymers; rheology; differential scanning calorimerty; 1H-NMR self-diffusion; Polymer chemistry; Polymerkemi;

   Sammanfattning : The goal of this work was to synthesize complex macromolecular architectures such as dendrimers and dendronized polymers, and evaluate the effect from the dendrons on the optical and material properties. The work presented in this doctoral thesis, Dendrimers and Dendronized Polymers - Synthesis and Characterization, is divided into one minor and one major part. LÄS MER

4. 3. Microbial and enzymatic syntheses of polymer building blocks through selective transformations of polyols and furans

   Författare :Mahmoud Sayed Ali Sayed; Bioteknik; []
   Nyckelord :Mycobacterium sp. MS1601; G. oxydans; oxidase; lipase; trimethylolpropane TMP ; 2; 2- bis hydroxymethyl butyric acid BHMB ; 5-hydroxymethyl furfural 5-HMF ; 5-hydroxymethyl-2-furan carboxylic acid HMFCA ; 2; 5-furandicarboxylic acid FDCA ; cyclic carbonate ; estrification; Biotransformation; polymer building blocks; product recovery; selective oxidation; bioprocess engneering; cell recycling; cell bleeding; DNA recombinant technology; in-silico analysis;

   Sammanfattning : AbstractTransition from fossil- to bio-based economy is a critical step towards reduction of greenhouse gas emissions and climate change, and hence for achievement of sustainable communities and environment. In order to be fossil-free, the chemical and material industry is in need of carbon-neutral building blocks from renewable resources for the diverse array of products that are currently produced from olefins and aromatics. LÄS MER

5. 4. Controlled Degradation of Polyester-Ethers Revealed by Mass Spectrometry Techniques

   Författare :Anders Höglund; Ann-Christine Albertsson; Jukka Seppälä; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Degradation products; biocompatibility; -caprolactone; 1; 5-dioxepan-2-one; 6-hydroxyhexanoic acid; 3- 2-hydroxyethoxy propanoic acid; oligomers; Polymer chemistry; Polymerkemi;

   Sammanfattning : The use of degradable biomedical materials in e.g. tissue engineering and controlled drug delivery has changed medical science during recent decades. The key question is to adapt the material with respect to mechanical properties, surface characteristics, and degradation profile to suit its intended application. LÄS MER

7. 5. Synthesis of Carbohydrate Mimics and Development of a Carbohydrate Epimerisation Method

   Författare :Clinton Ramstadius; Ian Cumpstey; Robert Madsen; Stockholms universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Carbohydrate Mimic; Ring-closing Metathesis; Carbohydrate Chemistry; Carbasugar; Aminocarbasugar; Pseudodisaccharide; Glycosidase and Lectin Inhibitors; Organic chemistry; Organisk kemi; organisk kemi; Organic Chemistry;

   Sammanfattning : In this thesis the synthesis of several hydrolytically stable carbohydrate mimics with the potential to function as glycosidase or lectin inhibitors are described. This work is presented in Chapters 2-5. LÄS MER