Sökning: "1H"

Visar resultat 1 - 5 av 191 avhandlingar innehållade ordet 1H.

  1. 1. Vanadate and Peroxovanadate Complexes of Biomedical Relevance : A speciation approach with focus on diabetes

    Författare :András Gorzsás; Lage Pettersson; Carlos F. G. C. Geraldes; Umeå universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Inorganic chemistry; vanadium; hydrogen peroxide; lactate; citrate; phosphate; alanyl serine; picolinic acid; speciation; formation constants; equilibrium; solution structure; potentiometry; NMR 51V; 31P; 13C; 1H ; Oorganisk kemi; Inorganic chemistry; Oorganisk kemi; oorganisk kemi; Inorganic Chemistry;

    Sammanfattning : Diabetes mellitus is one of the most threatening epidemics of modern times with rapidly increasing incidence. Vanadium and peroxovanadium compounds have been shown to exert insulin–like actions and, in contrast to insulin, are orally applicable. However, problems with side–effects and toxicity remain. LÄS MER

  3. 2. Susceptibility effects in MRI and 1H MRS. The spurious echo artifact and susceptibility measurements

    Författare :Åsa Carlsson; Göteborgs universitet; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; MRI; 1H MRS; susceptibility; spurious echo; artifact; artefact;

    Sammanfattning : When performing magnetic resonance (MR) experiments, a strong homogeneous magnetic field is often preferred, especially in clinical applications. However, all objects that are placed in the magnetic field will disturb the field homogeneity and cause local magnetic field gradients. LÄS MER

  4. 3. Mesoporous Silica Formed with Triblock Copolymers

    Författare :Katarina Flodström; Fysikalisk kemi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Fysikalisk kemi; 1H NMR; TEM; SAXS; in situ; mechanism of formation; cubic Ia3d; cubic Im3m; Mesoporous; synthesis; Pluronic; SBA-16; SBA-15; hexagonal p6mm; synchrotron SAXS; Physical chemistry; amphiphilic polymers; silica;

    Sammanfattning : The formation of highly ordered mesoporous silica materials, using PEO-PPO-PEO amphiphilic triblock copolymers (so-called Pluronics) as structure directing agents, has been studied. The materials are formed through the addition of a silica source to a polymer solution of low concentration (2.5 wt ) under acidic conditions. LÄS MER

  5. 4. Mechanistic Studies of Organocopper Chemistry by NMR Spectroscopy: Conjugate Additions to Alkynes and Alkenes

    Författare :Karolina Nilsson; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; cyanocuprate; organocopper reagents; ynones; lithium dimethylcuprate; 13C and 15N NMR spectroscopy; pi-complexes; mechanism; enoates; 6Li; 1H-HOESY; ynoates; conjugate addition;

    Sammanfattning : This thesis focuses on the mechanisms of organocopper reactions, in particular the reactions with activated alkynes (ynoates and ynones). These reactions are of interest in the formation of new highly functionalized double bonds with control of the stereochemistry. LÄS MER

  7. 5. Dissolved Organic Matter from a colloidal perspective

    Författare :Erika Andersson; Fysikalisk kemi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; dissolved organic matter; colloids; Microbial decomposition; hematite nanoparticles; soil; small angle scattering; light scattering; 1H NMR;

    Sammanfattning : Dissolved organic matter (DOM) is considered the most bioavailable fraction of soil, and thus play a key role in the cycling of carbon. Because of its mobility, DOM also forms the connection between terrestrial and aquatic systems, and constitutes an important vector for nutrients and contaminants. LÄS MER