Sökning: "π-conjugated"

Visar resultat 1 - 5 av 28 avhandlingar innehållade ordet π-conjugated.

1. 1. Single-­molecule spectroscopy of π-­conjugated polymers

   Författare :Oleg Mirzov; Kemisk fysik; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; fluorescence lifetime; low temperature; spectral diffusion; blinking; MEH-PPV; Single-molecule spectroscopy; π-conjugated polymers; 2D polarization; Monte Carlo; energy transfer;

   Sammanfattning : When applied to condensed-matter samples of large organic molecules, optical spectroscopy faces the problem of inhomogeneous broadening caused by the diversity of environments and conformations that sample molecules are subjected to. This severely limits the information that can be extracted from optical spectra. LÄS MER

3. 2. Phosphorus Centers in π-conjugated Systems

   Författare :Elisabet Öberg; Sascha Ott; Koop Lammertsma; Uppsala universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; phosphorus; phosphaalkene; phosphole; alkyne; π-conjugation; molecular electronics; Kemi; Chemistry;

   Sammanfattning : Single-molecular electronics and organic material electronics are expanding research fields that ultimately aim for a vast variety of different applications, ranging from organic light-emitting diodes, to novel ways to improve the performance and decrease the size of electronics components. To achieve these goals, research has to be focused both on the development of functional molecules, but also on device fabrication. LÄS MER

4. 3. Electron transport in π-conjugated systems

   Författare :Magnus Paulsson; Libero Zuppiroli; Linköpings universitet; []
   Nyckelord :;

   Sammanfattning : This thesis deals with theoretical studies of electron localization and conductance in conjugated molecular systems. Anderson localization of electrons is examined for nearly one-dimensional systems. This work was performed to understand the peculiar electronic properties of conducting polymers. LÄS MER

5. 4. Electron-lattice dynamics in π-conjugated systems

   Författare :Magnus Hultell (Andersson); Sven Stafström; Alessandro Troisi; Linköpings universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; charge transport; electron-lattice dynamics; polaron; adiabatic transport; electron localization; internal conversion; Computational physics; Beräkningsfysik;

   Sammanfattning : The work presented in this thesis concerns the dynamics in π-conjugated hydrocarbon systems. Due to the molecular bonding structure of these systems there exists a coupling between the electronic system and the phonons of the lattice. LÄS MER

7. 5. Ground and Excited State Aromaticity : Design Tools for π-Conjugated Functional Molecules and Materials

   Författare :Christian Dahlstrand; Henrik Ottosson; Miguel Solà; Uppsala universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; fulvene; fulvalene; polyfulvene; aromaticity; triplet state; excited state; Clar structure; polybenzenoid hydrocarbons PBH ; conjugated polymers; computational chemistry; optical spectroscopy; Kemi med inriktning mot organisk kemi; Chemistry with specialization in Organic Chemistry;

   Sammanfattning : The main focus of this thesis is on the aromaticity of the ground state and electronically excited states of π-conjugated molecules and polymers, as well as how aromaticity is connected to their properties.The electronic structures of polybenzenoid hydrocarbons (PBHs) were explored through density functional theory (DFT) calculations and the π-component of the electron localization function (ELFπ). LÄS MER