Sökning: "η3-allyl palladium complexes"

Hittade 3 avhandlingar innehållade orden η3-allyl palladium complexes.

  1. 1. Ligand Dependent Regioselectivity in Palladium Mediated Allylic Alkylation

    Författare :Charlotte Johansson; Göteborgs universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Palladium; allylic alkylation; η3-allyl palladium complexes; regioselectivity; PN-ligand; memory effects; dynamics; ligand effect; trans effects.;

    Sammanfattning : In this thesis, different aspects on ligand dependent regioselectivity in palladium mediated allylic alkylation have been studied. It is believed that the regioselectivity is a result of nucleophilic attack trans to phosphorous when applying ligands wih different donor atoms. LÄS MER

  3. 2. MECHANISTIC INVESTIGATIONS OF TRANSITION METAL CATALYZED REACTIONS

    Författare :Jonatan Kleimark; Göteborgs universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; alkene insertion; allylic alkylation; catalysis; cross coupling; density funtional theory; free energy surface; iron; kinetic investigation; Mizoroki-Heck reaction; nickel; palladium; reaction mechanism; sulfinylation; transition metal;

    Sammanfattning : Transition metal catalyzed reactions have had a large impact on the human progress for the last century. Several extremely important areas, such as the agricultural industry and the plastic industry, have benefited from this development. LÄS MER

  4. 3. Bispidine derivatives as molecular tools for studies of (-Allyl)palladium complexes : Ligand synthesis and analythical cpplications

    Författare :Andreas Axén; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chemistry; Kemi; Chemistry; Kemi; organisk kemi; Organic Chemistry;

    Sammanfattning : Determination of structural and stereochemical features of reaction intermediates in transition metal catalysed reactions is of central interest. Bispidine derivatives as ligands in (π-allyl)palladium complexes in combination with 1H NMR spectroscopy are shown to be useful tools for revealing structural characteristics of these reaction intermediates. LÄS MER