Sökning: "palladium memory effect"

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1. 1. Ligand Dependent Regioselectivity in Palladium Mediated Allylic Alkylation

   Författare :Charlotte Johansson; Göteborgs universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Palladium; allylic alkylation; η3-allyl palladium complexes; regioselectivity; PN-ligand; memory effects; dynamics; ligand effect; trans effects.;

   Sammanfattning : In this thesis, different aspects on ligand dependent regioselectivity in palladium mediated allylic alkylation have been studied. It is believed that the regioselectivity is a result of nucleophilic attack trans to phosphorous when applying ligands wih different donor atoms. LÄS MER