Sökning: "nucleophilic substitution reactions"
Visar resultat 1 - 5 av 19 avhandlingar innehållade orden nucleophilic substitution reactions.
1. Direct Catalytic Nucleophilic Substitution of Non-Derivatized Alcohols
Sammanfattning : This thesis focuses on the development of methods for the activation of the hydroxyl group in non-derivatized alcohols in substitution reactions. The thesis is divided into two parts, describing three different catalytic systems. LÄS MER
2. Organic Reactions i Organised Media
Sammanfattning : A common problem in synthetic organic chemistry is reactant incompatibility between lipophilic organic compounds and inorganic salts. The thesis reports an investigation of some organic reactions, involving incompatible substrate and nucleophile, performed in liquid crystalline phases and also in slurries of mesoporous materials with different symmetry. LÄS MER
3. Quantum Chemical Studies of Aromatic Substitution Reactions
Sammanfattning : In this thesis, density functional theory (DFT) is used to investigate the mechanisms and reactivities of electrophilic and nucleophilic aromatic substitution reactions (SEAr and SNAr respectively). For SEAr, the σ-complex intermediate is preceded by one (halogenation) or two (nitration) π-complex intermediates. LÄS MER
4. 18F/19F and 11C/14C kinetic isotope effects in nucleophilic substitution reactions
Sammanfattning : .... LÄS MER
5. Isotopes as Mechanism Spies : Nucleophilic Bimolecular Substitution and Monoamine Oxidase B Catalysed Amine Oxidation Probed with Heavy Atom Kinetic Isotope Effects
Sammanfattning : This thesis concerns the study of reaction mechanisms by means of kinetic isotope effects (KIEs). Studies of the nucleophilic bimolecular substitution (SN2) reaction had the dual purpose of improving our fundamental understanding of molecular reactivity and assessing the ability of kinetic isotope effects to serve as mechanistic tools. LÄS MER