Sökning: "molecular catalysts"

Visar resultat 1 - 5 av 157 avhandlingar innehållade orden molecular catalysts.

  1. 1. Molecular sieve film catalysts

    Författare :Olov Öhrman; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Chemical Technology; Kemisk teknologi;

    Sammanfattning : In this study, well defined ZSM-5 films were prepared on monoliths, ceramic foams, alumina beads, glass beads and crushed quartz glass by further refinement of a method originally developed at the division of Chemical Technology, Luleå University of Technology. The supports were seeded with silicalite-1 seeds and hydrothermally treated, either at 75 °C or at 150 °C in a single or several steps. LÄS MER

  2. 2. Artificial Photosynthesis: Molecular Catalysts for Water Oxidation

    Författare :Lei Wang; Licheng Sun; Hiroshi Imahori; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; artificial photosynthesis; water oxidation; ruthenium complexes; nickel complexes; cerium; photo-catalysts; photosensitizer; electrochemistry; immobilization.; Kemi; Chemistry; Energiteknik; Energy Technology;

    Sammanfattning : Artificial photosynthesis provides a promising solution to the future sustainable energy system. Water is the only suitably sufficient protons and electrons supplier by the reaction of water oxidation. However, this reaction is both kinetically and thermodynamically demanding, leading to a sluggish kinetics unless the introduction of a catalyst. LÄS MER

  3. 3. Biomimetic Transition Metal Catalysts : Insights from Theoretical Modeling

    Författare :Adam Johannes Johansson; Per E. M. Siegbahn; Margareta R. A. Blomberg; Per-Ola Norrby; Stockholms universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Catalysis; biomimetic; copper; non-heme iron; heme iron; O2 cleavage; H-atom transfer; radical chemistry; redox chemistry; thermo chemistry; entropy calculations; quantum chemistry; spin states; density functional theory DFT ; self-interaction error SIE .; Chemical physics; Kemisk fysik; kemisk fysik; Chemical Physics;

    Sammanfattning : The scientific interest in the chemistry of synthetic transition metal complexes is motivated by at least two arguments:1.These can be regarded as models of biological transition metal complexes, e.g. metalloenzymes, whose functions can be difficult to reveal in detail due to their complexity. LÄS MER

  4. 4. Structured molecular sieves : synthesis, modification and characterization

    Författare :Valeri Naydenov; Luleå tekniska universitet; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Chemical Technology; Kemisk teknologi;

    Sammanfattning : The work presented concerns synthesis of structured molecular sieves. The preparation procedure is based on the use of ion exchange resins as macrotemplates. Macroporous cation or anion exchange resin types were used depending on the molecular sieve type to be synthesized. LÄS MER

  5. 5. Design of Water Splitting Devices via Molecular Engineering

    Författare :Fusheng Li; Licheng Sun; Franc Meyer; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; electrochemical-driven water splitting; artificial photosynthesis; molecular catalysts; Kemi; Chemistry;

    Sammanfattning : Converting solar energyto fuels such as hydrogen by the reaction of water splitting is a promising solution for the future sustainable energy systems. The theme of this thesis is to design water splitting devices via molecular engineering; it concerns the studies of both electrochemical-driven and photo-electrochemical driven molecular functional devices for water splitting. LÄS MER