Sökning: "micellar structure"

Visar resultat 1 - 5 av 39 avhandlingar innehållade orden micellar structure.

  1. 1. NMR Studies of Colloidal Systems in and out of Equilibrium

    Författare :Pavel V. Yushmanov; Peter Stilbs; Terence Gosgrove; KTH; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; stopped-flow NMR; temperature-jump NMR; crossrelaxation; NMR; NMR probe; fluorosurfactant; micellar kinetics; micellar structure; Physical chemistry; Fysikalisk kemi;

    Sammanfattning : The Thesis describes (i) the development of add-on instrumentation extending the capabilities of conventional NMR spectrometers and (ii) the application of the designed equipments and techniques for investigating various colloidal systems. The new equipments are: Novel designs of stopped-flow and temperature–jump inserts intended for conventional Bruker wide-bore superconductive magnets. LÄS MER

  3. 2. Ternary Block Copolymer Systems - Phase Behaviour and Phase Structure

    Författare :Birgitta Svensson; Fysikalisk kemi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Theoretical chemistry; lyotropic; thermotropic; SANS; SAXS; scattering; semicrystalline; reverse micelle; micellar solution; liquid crystalline; phase diagram; phase behaviour; block copolymer; pluronic; poly ethylene oxide ; poly propylene oxide ; quantum chemistry; Teoretisk kemi; kvantkemi;

    Sammanfattning : Ternary isothermal (25°C) polyoxyalkylene triblock block copolymer ((EO)x(PO)y(EO)x where x is the number of ethylene oxide, EO, segments and y is the number of propylene oxide, PO, segments) systems with water and p-xylene as selective solvents for the PEO and PPO blocks, respectively, were chosen as study systems in this thesis as these ternary systems are good model systems for the self-assembly of block copolymers. The phase behaviour has been studied at varied block copolymer molecular weight and relative PEO/PPO block ratio. LÄS MER

  4. 3. Diffusion in cationic vesicle and micellar solutions- a NMR study

    Författare :Cecilia Groth; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; vesicles; Stopped-flow; micellar kinetics; water transport; DSC; Gemini surfactant; permeability; NOESY; Cationic surfactant; NMR diffusometry; extrusion;

    Sammanfattning : Double tailed cationic surfactants are the active component in softeners. In the beginning of the 90s the active component in softener formulations was changed from a hydrolytically stable dialkyl dimethyl ammonium chloride (dialkyl quat) to a cleavable and biodegradable product containing ester groups in the alkyl chains (dialkyl ester quat). LÄS MER

  5. 4. Nuclear Magnetic Relaxation in Micellar Solution and Lyotropic Liquid Crystals. Tools and Applications

    Författare :Ruslan Sitnikov; KTH; []
    Nyckelord :NMR; NMR relaxation dispersion; NMR spectrometer; low NMR frequencies; NMR duplexer; NMR preamplifier; NMR lock; surfactant systems; micellar solutions; lyotropic liquid crystals; cubic mesophase;

    Sammanfattning : Structurally, this Thesis is divided into two parts thatdescribe (i) the hardware development for NMR relaxationstudies and (ii) its applications for studies of the surfactantsystems.The developed hardware solutions allow to expand thefrequency range covered by conventional NMR spectrometers tomake NMR experiments feasible at resonance frequencies down to100 kHz. LÄS MER

  7. 5. Association in aqueous cationic surfactant-bile salt systems : a quantitative study of the phase equilibria, mixed micellar properties and structure

    Författare :Martin Swanson-Vethamuthu; Uppsala universitet; []
    Nyckelord :NATURAL SCIENCES; NATURVETENSKAP;

    Sammanfattning : .... LÄS MER