Sökning: "inorganic salt"

Visar resultat 1 - 5 av 58 avhandlingar innehållade orden inorganic salt.

1. 1. Molten Salt Electrolytes for Calcium Batteries

   Författare :Johanna Timhagen; Chalmers tekniska högskola; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Batteries; Metal anodes; Molten salt electrolytes; Calcium;

   Sammanfattning : Batteries are in higher demand than ever before as well as increased requirements in terms of energy and power density. The desire for higher energy density has meant that electrolytes are pushed above their electrochemical stability limits and hence they decompose, but typically this is under control and a new beneficial phase is created at the electrode surface; the solid electrolyte interphase (SEI). LÄS MER

3. 2. Towards Safer Lithium-Ion Batteries

   Författare :Marie Herstedt; Kristina Edström; Martin Winter; Uppsala universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Inorganic chemistry; lithium-ion batteries; photoelectron spectroscopy; surface film; thermal stability; electrolyte additive; graphite; lithium iron phosphate; Oorganisk kemi; Inorganic chemistry; Oorganisk kemi; Inorganic Chemistry; oorganisk kemi;

   Sammanfattning : Surface film formation at the electrode/electrolyte interface in lithium-ion batteries has a crucial impact on battery performance and safety. This thesis describes the characterisation and treatment of electrode interfaces in lithium-ion batteries. LÄS MER

4. 3. Interactions of Anticancer Active Platinum(II) Complexes with DNA

   Författare :Johan Kjellström; Bröstcancer-genetik; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Inorganic chemistry; polyelectrolyte; medium effects; salt dependence; DSC; CD; HPLC; oligonucleotide; hairpin; DNA; anticancer active platinum II compounds; kinetics; mechanism; Oorganisk kemi; Cytology; oncology; cancerology; Cytologi; onkologi; cancer;

   Sammanfattning : The kinetics and mechanism for interactions of the anticancer active platinum(II) complexes cis-[PtCl2(NH3)2)], cis-[PtCl2(NH3)(c-C6H11NH2)], and trans-[PtCl2-(NH3)(quinoline)] with DNA have been studied using a combination of HPLC, circular dichroism (CD), UV/vis spectroscopy, and differential scanning calorimetry (DSC). Reactions of the monoaqua forms (charge = +1) of these complexes with single-stranded DNA oligonucleotides, typically between 13-17 bases long, were found to depend on i) the composition of the reaction medium, ii) the exact nature and location of the platination target, and iii) on the DNA structure. LÄS MER

5. 4. Model Systems for Metal - DNA Interactions. With a Focus on Anticancer Active Platinum(II) Complexes

   Författare :Anna Ericson; Kemiska institutionen; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; kinetics; DNA; poly d T ; guanine; 6-thioinosine-5 -monophosphate; 6-thio-2 -deoxyinosine; 4-thiouridine-5 -monophosphate; 4-thio-2 -deoxyuridine; palladium II ; Gold III ; platinum II ; mechanism; salt effect; activation parameters; Inorganic chemistry; Oorganisk kemi;

   Sammanfattning : Reactions of trans-dicyanodichloroaurate(III) trans-dibromodicyanoaurate(III), trans-diamminedichlorogold(III), cis-diammine(aqua)chloroplatinum(II), cis-ammineaqua-(cyclohexylamine)chloroplatinum(II), chloro(terpyridine)platinum(II) and chloro-(diethylenetriaminepalldium(II) with dimethyl sulfide, thionucleosides, thionucleotides and thione- and guanine-containing 17-mer oligonucleotides have been investigated by use of conventional and high-pressure stopped-flow spectrophotometry and HPLC technique as a function of ionic strength, pH, temperature and pressure in aqueous solutions. The mechanism and rate of oxidation of dimethyl sulfide by gold(III) complexes depends on the concentration of free halide. LÄS MER

7. 5. Tailored Reaction Media for the Synthesis of Subvalent Cluster Compounds

   Författare :Josefin Åkerstedt; Lars Kloo; Sven Lidin; Ulf Gedde; KTH; []
   Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Chemistry; Kemi; Inorganic Chemistry;

   Sammanfattning : Different synthetic approaches and modifications to reaction media have been applied in order to find new routes to the synthesis of main-group clusters and transition metal compounds. The focus has been on the Group 15 element bismuth and the transition metal palladium. LÄS MER