Sökning: "hypervalent carbon"
Hittade 5 avhandlingar innehållade orden hypervalent carbon.
1. Lowcoordinated Silicon and Hypercoordinated Carbon : Structure and Stability of Silicon Analogs of Alkenes and Carbon Analogs of Silicates
Sammanfattning : Quantum chemical studies on lowcoordinated group 14-16 compounds have been performed. This thesis focuses particularly on silenes influenced by reverse Siδ-=Cδ+ bond polarization. Hypercoordinated carbon compounds are also studied. LÄS MER
2. Hypervalent Iodine Reagents in Metal-Free Arylations and Vinylations : Investigation of Suitable Coupling Partners and Synthesis of New Reagents
Sammanfattning : This thesis concerns the development of metal-free reactions to obtain carbon-heteroatom and carbon-carbon bonds. This is achieved by transferring carbon ligands from hypervalent iodine reagents to suitable nucleophiles. LÄS MER
3. Synthesis of Organofluorine Compounds and Allenylboronic Acids - Applications Including Fluorine-18 Labelling
Sammanfattning : This work is focused on two areas: the chemistry of organofluorine and organoboron compounds. In the first chapter, a copper-catalysed synthesis of tri- and tetrasubstituted allenylboronic acids is presented. Extension of the same method leads to allenylboronic esters. LÄS MER
4. Diaryliodonium Salts : Synthesis, Applications and Computational Investigations
Sammanfattning : Organic chemists have the ability to create complex organic molecules by connecting molecular building blocks in different ways. To name a few, these molecules are used as medicines, pesticides or in our household electronics, and are therefore crucial to life as we know it. LÄS MER
5. Development of Catalytic ElectrophilicTrifluoromethylation and Fluorination Methods
Sammanfattning : This thesis is focused on development of new catalytic, electrophilic fluorination and trifluoromethylation methods of alkenes. These reactions were carried out using hypervalent trifluoromethyl and fluoroiodine reagents.The first project involved copper catalyzed oxytrifluoromethylation of terminal alkenes and alkynes. LÄS MER