Sökning: "bulk polymerization"

Visar resultat 1 - 5 av 20 avhandlingar innehållade orden bulk polymerization.

1. 1. Synthesis and Characterization of Sec-Packings Based on Trimethylolpropane Trimethacrylate

   Författare :Andrea Schmid; Chalmers tekniska högskola; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; bulk polymerization; N; hydrophilic gels; separation; methyl methacrylate; hydrophobic networks; acrylamide; porous networks; Suspension; N -methylene-bis-acrylamide; chemically crosslinked networks; dry gels; polysaccharide standards; distilled water; copolymerization; trimethylolpropane trimethacrylate;

   Sammanfattning : Suspension and bulk polymerization of trimethylolpropane trimethacrylate (TRIM) and copolymerization of TRIM with methyl methacrylate (MMA) resulted in porous, hydrophobic, and chemically crosslinked networks. Copolymerization of TRIM with acrylamide (AA) and with N,N'-methylene-bis-acrylamide (bis-AA) resulted in hydrophilic gels. LÄS MER

3. 2. Synthesis of functional degradable polymers by radical ring-opening polymerization

   Författare :Jenny Undin; Ann-Christine Albertsson; Mats Johansson; Monica Ek; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; tissue engineering; ring-opening polymerization; 2; 2´-azoisobutyronitrile; cyclic ketene acetals; 2-methylene- 1; 3; 6-trioxocane; 2-methylene- 1; 3-dioxepane; vinyl acetate; coopolymerization;

   Sammanfattning : The increased demand for understanding cell-material interactions and subsequently create personalized implants for tissue engineering has resulted in an increased interest in developing new monomers with functional groups. The focus of the work presented in this thesis has been on the synthesis of functional monomers and the polymerization of these into functional amorphous aliphatic polyesters. LÄS MER

4. 3. Strategies for cellulose fiber modification

   Författare :Per Persson; KTH; []
   Nyckelord :Candida antarctica lipase B; cationic catalysis; cellulose-binding module; dendrimer; enzymatic polymerization; fiber modification; silica-cast replica; sol-gel mineralization; organocatalysis; xyloglucan endotransglycosylase;

   Sammanfattning : This thesis describes strategies for and examples ofcellulose fiber modification.The ability of an engineered biocatalyst, acellulose-binding module fused to theCandida antarcticalipase B, to catalyze ring-openingpolymerization of e-caprolactone in close proximity tocellulose fiber surfaces was explored. LÄS MER

5. 4. Dendrimers and dendronized polymers : synthesis and characterization

   Författare :Andreas Nyström; Anders Hult; A. Dieter Schlüter; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Dendrimers; dendronized polymers; atom transfer radical polymerisation; ring-opening metathesis polymerization; reversible addition-fragmentation chain transfer polymerization; 2; 2-bis methylol propionic acid; tri-block copolymers; rheology; differential scanning calorimerty; 1H-NMR self-diffusion; Polymer chemistry; Polymerkemi;

   Sammanfattning : The goal of this work was to synthesize complex macromolecular architectures such as dendrimers and dendronized polymers, and evaluate the effect from the dendrons on the optical and material properties. The work presented in this doctoral thesis, Dendrimers and Dendronized Polymers - Synthesis and Characterization, is divided into one minor and one major part. LÄS MER

7. 5. Design of renewable and functional polyamides and polyhydroxyurethanes with tunable structure-property relationships

   Författare :Charalampos Pronoitis; Karin Odelius; Minna Hakkarainen; Stefan Naumann; KTH; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; polyamide; polyhydroxyurethane; polyester; ring-opening aminolysis; ring-opening polymerization; covalent adaptable network; copolymer; complex architecture; polyamid; polyhydroxyuretan; polyester; ringöppningsaminolys; ringöppningspolymerisation; dynamiska nätverk; sampolymer; komplex arkitektur; Fiber- och polymervetenskap; Fibre and Polymer Science;

   Sammanfattning : Redesigning polymeric materials and rethinking their use is imperative in the prospect of a more sustainable future. Critical aspects in this endeavor are the use of renewable monomers to decrease the environmental footprint, implementing green syntheses and production processes and the design for increased recyclability as an end-of-life option to diverge from the generation of plastic waste. LÄS MER