Sökning: "borane"
Visar resultat 1 - 5 av 10 avhandlingar innehållade ordet borane.
1. Synthesis and Applications of P-chirogenic Phosphine Boranes
Sammanfattning : AbstractThis thesis reports the independent synthesis of both enantiomers of P-chirogenic phosphine ligands and the building blocks thereof, which are suitable for parallel synthesis efforts and for the generation of more diverse libraries of P-chirogenic compound. The use of P-chirogenic phosphine boranes in transition metal-catalyzed reactions, such as palladium-catalyzed allylic alkylation and amination, is also described. LÄS MER
2. Metal Mediated Synthesis. Synthetic and Mechanistic Investigations of Conjugate Addition and Reductive Amination
Sammanfattning : The thesis is divided into two separate parts, one treating conjugate addition and the other reductive aminations. The first part of the thesis is concerned with organocopper promoted conjugate addition to .alfa.,. LÄS MER
3. Synthetic studies on naphthoxylosides - labeled compounds and mechanistic studies on acetals
Sammanfattning : Labeled analogs to an antiproliferative naphthoxyloside have been synthesized and evaluated. Our investigations have shown that the fluorescently labeled analogs are poor structural analogs, and the physical and biological properties are altered to a large extent. LÄS MER
4. Synthesis of some oligosaccharides with D-galacto- and D-gluco-configuration and reductive opening of carbo-hydrate acetals
Sammanfattning : Syntheses of the following oligosaccharides, required for immunological studies. are discussed: £-trifluoroacetamidophenyl O-a-D-glucopyranosyl-(1+4)-a-D-galactopyranoside, ß-trifluoroacetamidophenyl O-a-D-glucopyranosyl-(1 + 6)-a-D-galactopyranoside, 8-methoxy- carbonyloct-1-yl 0-a-D-galactopyranosyl-(1+3)-fi-ß~9"9alact°Pyranosyl- (1+4)-2-acetamido-2-deoxy-ß-D-glucopyranoside, methyl û-a-D-fuco- pyranosyl-(1+4)-ß-D-galactopyranoside, methyl û-a-D-galactopyranosyl- (1+4)-ß-D-fucopyranoside and methyl ß-a-D-fucopyranosyl-(1+4)-ß-D- fucopyranoside. LÄS MER
5. Acetals - Exploring reactivity for improved carbohydrate synthesis
Sammanfattning : In my research, I have explored various aspects of acetals and their reactivity. Acetals have a central role in carbohydrate chemistry as an inherent functionality and as versatile protecting groups. The first part of the thesis summarizes results on regioselective reductive openings of benzylidene acetals. LÄS MER