Sökning: "alkylation"

Visar resultat 1 - 5 av 77 avhandlingar innehållade ordet alkylation.

  1. 1. 1. Asymmetric aldol and alkylation reactions using pyrrolidine-based chiral auxiliaries 2. Syntheses of pine sawfly pheromone precursors and structurally related compounds

    Författare :Fredrik Andersson; KTH; []
    Nyckelord :Chiral auxiliary; Stereoselectivity; Lewis acid; Aldol; Alkylation; Sex pheromone; Pine sawfly; Lipase; Synthesis; Diprion nipponica; Macrodiprion memoralis; Microdiprion pallipes; ;

    Sammanfattning : This thesis describes the syntheses of the 1-propionylatedauxiliaries (S)-(− )-2-(pyrrolidin-2-yl)propan-2-ol and (S)-(− )-2-(1-methoxy-1-methylethyl)pyrrolidine andtheir use in asymmetric aldol and alkylation reactions. Thesynthesis of 1-propionylated (2S,4R) 2-{4-[(tert-butyldimethylsilyl)oxy]pyrrolidin-2-yl}propan-2-olis also described. LÄS MER

  3. 2. 1. Asymmetric aldol and alkylation reactions using pyrrolidine-based chiral auxiliaries 2. Syntheses of pine sawfly pheromone precursors and structurally related compounds

    Författare :Fredrik Andersson; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Chiral auxiliary; Stereoselectivity; Lewis acid; Aldol; Alkylation; Sex pheromone; Pine sawfly; Lipase; Synthesis; Chemistry; Kemi;

    Sammanfattning : .... LÄS MER

  4. 3. Alkylation and Hydrodearomatization over Zeolite cCatalysts

    Författare :Jun-Jun Yuan; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Acid catalysts; ZSM-5 catalysts; ethylbenzene; toluene; temperature; diesel fuel; hydrodearomatization; benzene; acidic protons; activity and selectivity; aqueous ethanol; Pt Y zeolite; gasoline; pressure; GC; diethylbenzene; Hydrocracking; SiO2 Al2O3 ratio; alkylation of aromatics; Brønsted acids;

    Sammanfattning : The alkylation of aromatic compounds is widely used in the large-scale synthesis of petrochemicals, and a great variety of fine chemicals and intermediates. Acid catalysts used for alkylation of aromatic hydrocarbons are Brønsted acids containing acidic protons. LÄS MER

  5. 4. Ligand Dependent Regioselectivity in Palladium Mediated Allylic Alkylation

    Författare :Charlotte Johansson; Göteborgs universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Palladium; allylic alkylation; η3-allyl palladium complexes; regioselectivity; PN-ligand; memory effects; dynamics; ligand effect; trans effects.;

    Sammanfattning : In this thesis, different aspects on ligand dependent regioselectivity in palladium mediated allylic alkylation have been studied. It is believed that the regioselectivity is a result of nucleophilic attack trans to phosphorous when applying ligands wih different donor atoms. LÄS MER

  7. 5. Studies of Hydrogenations and Isomerizations of Olefins and Alkylations of Amines Using Iridium Catalysts

    Författare :Jia-Qi Li; Pher Andersson; Jianliang Xiao; Uppsala universitet; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Iridium; Asymmetric; Hydrogenation; Isomerization; Alkylation; Organisk kemi; Organic Chemistry;

    Sammanfattning : This thesis describes three types of reactions that were carried out using iridium catalysts.The first type is the iridium-catalyzed asymmetric hydrogenation of olefins. In paper I, the preparation of a new type of bicyclic thiazole-phosphine based iridium complex was described. LÄS MER