Sökning: "Protonic conductivity"

Visar resultat 1 - 5 av 8 avhandlingar innehållade orden Protonic conductivity.

1. 1. Proton conductivity in acceptor-doped lanthanide based pyrochlore oxides

   Författare :Karinh Eurenius; Göteborgs universitet; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Pyrochlore; Rietveld refinement; Proton conductivity; Electrical impedance spectroscopy; Concentration Cell Electromotive Force Method.;

   Sammanfattning : A high interest in developing new materials for SOFC applications in the temperature range of approximately 200–500 C has been growing lately. The lower activation energies for proton (H+) mobility can give higher conductivity in this temperature range. LÄS MER

3. 2. Functional Oxide Materials exhibiting Ionic Conductivity for Future Energy Conversion Needs

   Författare :FRANCIS GACHAO KINYANJUI; Chalmers tekniska högskola; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; neutron diffraction; perovskites; oxygen deficient perovskites; BaSnO3; Rietveld refinements; BaZrO3; in-situ cells; proton conduction; deuteron position; Ba3In2ZrO8;

   Sammanfattning : Fuel cells are electrochemical devices that transform the chemical energy in hydrogen and oxygen into electrical energy at high efficiencies and produce only water vapour emissions. Materials with the perovskite or fluorite structure types are commonly employed as the ion conducting ceramic electrolyte membranes in intermediate and high temperature fuel cells. LÄS MER

4. 3. Intermediate Temperature Solid Ionic Conductors and Fuel Cells

   Författare :Zhu Bin; Chalmers tekniska högskola; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; molten phase; bulk and interfacial conduction; intermediate temperature; salt-ceramic composites; solid state proton conductors and fuel cells; blocked and non-blocked mobile species; ionic and protonic conduction and diffusion; oxyacid salts;

   Sammanfattning : Novel solid proton conductors based on oxyacid salts and salt-ceramic composites and intermediate temperature fuel cells have been developed in this thesis work. The discovery of proton conduction in these materials introduces a new concept of proton conductors and starts a new research field - Intermediate Temperature Solid Proton Conductors and Fuel Cells. LÄS MER

5. 4. Exploratory Study of Novel Materials Used for Intermediate Temperature Solid Oxide Fuel Cell (IT-SOFC) Electrolytes

   Författare :Junfu Bu; Pär Jönsson; Zhe Zhao; Christopher Knee; KTH; []
   Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Hafnium oxide; Solid oxide fuel cells SOFCs ; Electrolyte; Electrochemical impedance spectroscopy; Solid state reaction method; Solid state reactive sintering SSRS ; Ionic conductivity; oxygen ion conductivity; Protonic conductivity; Composite electrolyte.;

   Sammanfattning : Currently, yttria-stabilized zirconia (YSZ) is still the dominant electrolyte material in commercial SOFC applications. But it has severe drawbacks due to its high operating temperatures. In present work, two electrolyte materials: Hf0.69Y0. LÄS MER

7. 5. Proton Conducting Ceramics; Synthesis, Characterization and Sample Cell Environments

   Författare :FRANCIS GACHAO KINYANJUI; Chalmers tekniska högskola; []
   Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; perovskites; neutron diffraction; Rietveld refinements; BaSnO3; in-situ cell; deuteron position; proton conduction; BaZrO3;

   Sammanfattning : Acceptor doped Perovskite ceramics have been shown to exhibit high levels of protonic conduction in humid atmospheres. However significant grain boundary resistance and long sintering times required to achieve sufficient grain size growth has hindered their widespread application as electrolyzers, fuel cells and gas separation membranes. LÄS MER