Sökning: "Phase equilibria"

Visar resultat 11 - 15 av 46 avhandlingar innehållade orden Phase equilibria.

  1. 11. The Use of Supercritical Fluids to Reduce the Number of Phases in Catalytic Hydrogenation: The Reaction of Fatty Acid Methyl Esters to Fatty Alcohols

    Författare :Sander van den Hark; Chalmers tekniska högskola; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; fatty alcohols; single phase; deactivation; mass transport; phase reduction; supercritical fluids; hydrogenation; propane; kinetics; catalysis;

    Sammanfattning : Supercritical fluids have unique properties - between those of liquids and gases - making them attractive reaction media. In this study, propane was used to change a heterogeneous catalyst from being substrate-covered in gas-liquid hydrogenation reactions into hydrogen-covered in our experiments. LÄS MER

  2. 12. Phase equilibria and thermodynamic properties of high-alloy tool steels : theoretical and experimental approach

    Författare :Johan Bratberg; John Ågren; Bengt Hallstedt; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; thermodynamic modelling; thermodynamic calculations; tool steels; high-speed steels; CALPHAD; Other materials science; Övrig teknisk materialvetenskap;

    Sammanfattning : The recent development of tool steels and high-speed steels has led to a significant increase in alloy additions, such as Co, Cr, Mo, N, V, and W. Knowledge about the phase relations in these multicomponent alloys, that is, the relative stability between different carbides or the solubility of different elements in the carbides and in the matrix phase, is essential for understanding the behaviour of these alloys in heat treatments. LÄS MER

  3. 13. Recovery of Scandium using Antisolvent Crystallization in the Valorization of Scandium-containing Waste Streams

    Författare :Edward Peters; Kerstin Forsberg; Michael Svärd; Jens-Petter Andreassen; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Antisolvent crystallization; ammonium scandium hexafluoride; ammonium metal fluorides; phase equilibria; solubility; supersaturation; seeding; agitation mechanism; crystal size distribution; morphology; Chemical Engineering; Kemiteknik;

    Sammanfattning : Scandium is widely dispersed in the earth’s crust and is rarely concentrated in ores, and a viable option to guarantee a secure supply of scandium is to recover the metal from waste streams of other mining and metallurgical facilities. The valorization of such streams to recover metals of value is a prerequisite to alleviate the global shortages of scandium and other rare earth elements. LÄS MER

  4. 14. Crystallographic Studies of Ternary Chalcogenides and Organic Semiconductors

    Författare :Céline Besnard; Centrum för analys och syntes; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; phase equilibria; Kondenserade materiens egenskaper:struktur; egenskaper termiska och mekaniska ; kristallografi; fasjämvikt; crystallography; thermal and mechanical properties; Condensed matter:stucture; thiazine derivatives; quinoline derivatives; hexacene-quinone; substituted tetracene; rubrene derivatives; manganese telluride; organic semiconductors; niobium sulfide intercalation compounds; thiospinel;

    Sammanfattning : X-ray diffraction methods have been used to study the crystal structure of different compounds, both organic and inorganic. The inorganic compounds were all synthesized by solid state reactions. A new compound, Re4As6S3, was synthesized and its structure was solved by Rietveld methods. LÄS MER

  5. 15. Generation and Applications of Short-Pulse X-ray Radiation

    Författare :Michael Harbst; Atomfysik; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; egenskaper termiska och mekaniska ; Kondenserade materiens egenskaper:struktur; crystallography; phase equilibria; Material science; Condensed matter:stucture; thermal and mechanical properties; time-resolved; X-ray diffraction; kristallografi; fasjämvikt; Material technology; Materiallära; materialteknik;

    Sammanfattning : This thesis summarizes work using hard X-ray radiation on nanosecond and picosecond timescales. The focus is on the experimental part including detailed descriptions of setups for laser pumped - X-ray probe experiments. X-ray diffraction is sensitive to structural properties on the length scale of chemical bonds. LÄS MER