Sökning: "Lamellar phase"

Visar resultat 1 - 5 av 56 avhandlingar innehållade orden Lamellar phase.

  1. 1. Polymer effects on microemulsions and lamellar phases

    Författare :Håkan Bagger-Jörgensen; Fysikalisk kemi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Poisson-Boltzmann equation; hard sphere; osmometry; small angle scattering; phase behaviour; hydrophobically modified polyelectrolyte; hydrophobically modified polymer; nonionic surfactant; microemulsion; lamellar phase; undulation force; Physical chemistry; Fysikalisk kemi;

    Sammanfattning : The main part of this thesis deals with the effects of adsorbing and non-adsorbing polymers when mixed with microemulsion droplets and bilayers in a lamellar phase. The phase behaviour, microstructure and interactions in a nonionic surfactant/ water/ oil-system, comprising penta ethylene oxide dodecyl ether (C12E5) and decane, was investigated. LÄS MER

  2. 2. Ternary Block Copolymer Systems - Phase Behaviour and Phase Structure

    Författare :Birgitta Svensson; Fysikalisk kemi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Theoretical chemistry; lyotropic; thermotropic; SANS; SAXS; scattering; semicrystalline; reverse micelle; micellar solution; liquid crystalline; phase diagram; phase behaviour; block copolymer; pluronic; poly ethylene oxide ; poly propylene oxide ; quantum chemistry; Teoretisk kemi; kvantkemi;

    Sammanfattning : Ternary isothermal (25°C) polyoxyalkylene triblock block copolymer ((EO)x(PO)y(EO)x where x is the number of ethylene oxide, EO, segments and y is the number of propylene oxide, PO, segments) systems with water and p-xylene as selective solvents for the PEO and PPO blocks, respectively, were chosen as study systems in this thesis as these ternary systems are good model systems for the self-assembly of block copolymers. The phase behaviour has been studied at varied block copolymer molecular weight and relative PEO/PPO block ratio. LÄS MER

  3. 3. Catanionic Surfactant Mixtures and Binary Systems of Modified Fatty Acid Surfactants. Phase Equilibria and Structure

    Författare :Malin Bydén Sjöbom; Fysikalisk kemi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; coacervation; asymmetry; bile salt; didodecyldimethylammonium bromide; Physical chemistry; Fysikalisk kemi; catanionic surfactant mixture; intermediate phase; a-methylsubstituted sodium carboxylate; dodecylpyridinium bromide; ionic surfactant; polarizing microscopy; FT-PGSE self-diffusion; 2H NMR; SAXS; liquid crystal; micelle; phase equilibria; phase diagram;

    Sammanfattning : Surfactant self-assembly is an important phenomenon that occurs in a number of processes in our everyday life. It is important to understand the forces and parameters that control and influence the self-assembly, as this knowledge can be used both in order to design surfactant systems with desired properties and for creating model systems, for example for biological processes. LÄS MER

  4. 4. Lipid bilayers versus monolayers- Sponge phases and skin lipid domains

    Författare :Katarina Ekelund; Livsmedelsteknik; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; fatty acids; Langmuir-Blodgett films; AFM; domains; stratum corneum; bilayer curvature; lipids; glycerol monooleate; phase behaviour; sponge phase; L3 phase; Livsmedelsteknik; cholesterol; Food and drink technology;

    Sammanfattning : The L3, or sponge, phase is a thermodynamically stable isotropic liquid consisting of a surfactant membrane in aqueous solution. A solvent induced L3 phase is shown in systems of solvent, monoolein and water. LÄS MER

  5. 5. Controlling Structure and Water Miscibility of Polyion - Surfactant Ion Complex Salts

    Författare :Jens Norrman; Fysikalisk kemi; []
    Nyckelord :NATURVETENSKAP; NATURAL SCIENCES; Physical chemistry; Fysikalisk kemi; phase diagram; cubic Pm3n; hexagonal; lamellar; self diffusion; PFG NMR; SAXS; liquid crystals; polymer; counterion; complex; polyelectrolyte; surfactant;

    Sammanfattning : The interaction between poylions and oppositely charged surfactant ions has been investigated. This has been done by using the pure complex salt (polyion + surfactant ion) as a point of departure. Different parameters of the complex salt have been varied in a systematic way and the effect on structure and water miscibility has been investigated. LÄS MER