Sökning: "Activity coefficient"

Visar resultat 1 - 5 av 86 avhandlingar innehållade orden Activity coefficient.

  1. 1. Investigations intothe crystallization of butyl paraben

    Författare :Huaiyu Yang; Åke Rasmuson; Mårten Behm; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Butyl paraben; Solubility; Thermodynamic; Activity; Activity coefficient; Second order correlation; Liquid-liquid phase separation; Ternary phase diagram; Nucleation; Induction time; Free energy; Interfacial energy; Nuclei critical radius Cooling crystallization; Evaporation crystallization; Chemical engineering; Kemiteknik;

    Sammanfattning : In thisproject, solubility of butyl paraben in 7 puresolvents and 5 ethanol aqueous solvents has been determined at from 1 ℃to 50 ℃. Thermodynamic properties of butyl paraben have been measured by DifferentialScanning Calorimetey. LÄS MER

  3. 2. Crystallization of Parabens : Thermodynamics, Nucleation and Processing

    Författare :Yang Huaiyu; Åke Rasmuson; Joop ter Horst; KTH; []
    Nyckelord :MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Nucleation; Induction time; Interfacial energy; Ethyl paraben; Propyl paraben; Butyl paraben; Methanol; Ethanol; Propanol; Acetone; Ethyl acetate; Solubility; Thermodynamics; Activity; Activity coefficient; Liquid-liquid phase separation; Ternary phase diagram; Melting point; Boiling point; Polarity; Cooling crystallization; Sandwich crystal; Porous; Particle Vision and Measurement; Focused Beam Reflectance Method; Infrared Spectroscopy; Confocal Raman Microscopy; X-Ray Diffraction; Differential Scanning Calorimetry; SRA - E-Science SeRC ; SRA - E-vetenskap SeRC ;

    Sammanfattning : In this work, the solubility of butyl paraben in 7 pure solvents and in 5 different ethanol-water mixtures has been determined from 1 ˚C to 50 ˚C. The solubility of ethyl paraben and propyl paraben in various solvents has been determined at 10 ˚C. LÄS MER

  4. 3. Thermodynamic modelling of black liquor-related solutions. Pitzer method for estimating activities, solubilities and boiling point rise

    Författare :Marta Anna Bialik; Chalmers tekniska högskola; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; activity coefficient; black liquor; boiling point rise elevation ; osmotic coefficient; solubility; Pitzer method; sodium sulphate dicarbonate; burkeite;

    Sammanfattning : Black liquor is considered as being one of the most important process streams as far as the design and optimization of kraft pulp mills are concerned. Many methods have been developed in order to describe and, possibly, predict its physico-chemical properties. Most of them are, however, empirical methods that are difficult to generalize. LÄS MER

  5. 4. Thermodynamic Modelling of Electrolyte Solutions with Application to the Pulp and Paper Industry

    Författare :Anders Jaretun; Avdelningen för kemiteknik; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Potassium; Chloride; Chemical recovery; Leaching; Crystallization; Kraft pulping; Non-process elements; Solubility; Local composition; Excess properties; Osmotic coefficient; Electrolytes; Activity coefficient; Wood; pulp and paper technology; Pappers- och massateknik;

    Sammanfattning : A thermodynamic model for electrolyte solutions has been derived for binary and multicomponent solutions up to very high molalities. The model was extensively tested on 163 binary aqueous electrolyte systems up to very high molalities, and the results show that the model represents mean ionic activity coefficients and osmotic coefficients very accurately. LÄS MER

  7. 5. Extraction of Metal Values : Thermodynamics of Electrolyte Solutions and Molten Salts Extraction Process

    Författare :Xinlei Ge; Seshadri Seetharaman; Katsunori Yamaguchi; KTH; []
    Nyckelord :TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Electrolyte solutions; activity coefficient; osmotic coefficient; freezing point depression; boiling point elevation; Materials science; Teknisk materialvetenskap;

    Sammanfattning : Over the past centuries, a number of process routes for extraction of metal values from an ore or other resources have been developed. These can generally be classifiedinto pyrometallurgical, hydrometallurgical or electrometallurgical routes. LÄS MER